Electrochemical performance and kinetics of LiFePO4/C cathode in a low-temperature electrolyte

Jingwen Yao; Feng Wu; Borong Wu; Xinping Qiu; Chunwei Yang; Ning Li

Electrochemical performance and kinetics of LiFePO₄/C cathode in a low-temperature electrolyte

Jingwen Yao
, Feng Wu
, Borong Wu^*
, Xinping Qiu
, Chunwei Yang
, Ning Li

^*Corresponding author for this work

School of Material Science and Engineering

Tsinghua University
Beijing Institute of Technology

Research output: Contribution to conference › Paper › peer-review

1 Citation (Scopus)

Abstract

The electrochemical performance of LiFePO₄/C cathode in a carbonate-based electrolyte (1.0M LiPF₆/EC-DMC-PC-FEC) was tested in coin type cells at low temperatures. The discharge capacities of the LiFePO4/C cathode were about 161.6mAh/g (20°C), 141.4mAh/g (-10°C) and 112.9mAh/g (-20°C) at 0.1C charge-discharge rate. The electrode kinetics of LiFePO ₄/C cathode was determined at different temperatures using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The analyses demonstrate that the sluggish of charge-transfer reaction on the LiFePO ₄/C-electrolyte interface and the dramatic decrease in lithium ion diffusivity in the bulk LiFePO₄/C material were the key performance limiting factors at low temperature.

Original language	English
Publication status	Published - 2010
Event	25th World Battery, Hybrid and Fuel Cell Electric Vehicle Symposium and Exhibition: Sustainable Mobility Revolution, EVS 2010 - Shenzhen, China Duration: 5 Nov 2010 → 9 Nov 2010

Conference

Conference	25th World Battery, Hybrid and Fuel Cell Electric Vehicle Symposium and Exhibition: Sustainable Mobility Revolution, EVS 2010
Country/Territory	China
City	Shenzhen
Period	5/11/10 → 9/11/10

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Fluoroethylene carbonate
Lithium ion batteries
Low-temperature electrolyte

Cite this

@conference{bc8831c3d74148479521d02a7271a57b,

title = "Electrochemical performance and kinetics of LiFePO4/C cathode in a low-temperature electrolyte",

abstract = "The electrochemical performance of LiFePO4/C cathode in a carbonate-based electrolyte (1.0M LiPF6/EC-DMC-PC-FEC) was tested in coin type cells at low temperatures. The discharge capacities of the LiFePO4/C cathode were about 161.6mAh/g (20°C), 141.4mAh/g (-10°C) and 112.9mAh/g (-20°C) at 0.1C charge-discharge rate. The electrode kinetics of LiFePO 4/C cathode was determined at different temperatures using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The analyses demonstrate that the sluggish of charge-transfer reaction on the LiFePO 4/C-electrolyte interface and the dramatic decrease in lithium ion diffusivity in the bulk LiFePO4/C material were the key performance limiting factors at low temperature.",

keywords = "Fluoroethylene carbonate, Lithium ion batteries, Low-temperature electrolyte",

author = "Jingwen Yao and Feng Wu and Borong Wu and Xinping Qiu and Chunwei Yang and Ning Li",

year = "2010",

language = "English",

note = "25th World Battery, Hybrid and Fuel Cell Electric Vehicle Symposium and Exhibition: Sustainable Mobility Revolution, EVS 2010 ; Conference date: 05-11-2010 Through 09-11-2010",

}

Electrochemical performance and kinetics of LiFePO₄/C cathode in a low-temperature electrolyte. / Yao, Jingwen; Wu, Feng; Wu, Borong et al.
2010. Paper presented at 25th World Battery, Hybrid and Fuel Cell Electric Vehicle Symposium and Exhibition: Sustainable Mobility Revolution, EVS 2010, Shenzhen, China.

Research output: Contribution to conference › Paper › peer-review

TY - CONF

T1 - Electrochemical performance and kinetics of LiFePO4/C cathode in a low-temperature electrolyte

AU - Yao, Jingwen

AU - Wu, Feng

AU - Wu, Borong

AU - Qiu, Xinping

AU - Yang, Chunwei

AU - Li, Ning

PY - 2010

Y1 - 2010

N2 - The electrochemical performance of LiFePO4/C cathode in a carbonate-based electrolyte (1.0M LiPF6/EC-DMC-PC-FEC) was tested in coin type cells at low temperatures. The discharge capacities of the LiFePO4/C cathode were about 161.6mAh/g (20°C), 141.4mAh/g (-10°C) and 112.9mAh/g (-20°C) at 0.1C charge-discharge rate. The electrode kinetics of LiFePO 4/C cathode was determined at different temperatures using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The analyses demonstrate that the sluggish of charge-transfer reaction on the LiFePO 4/C-electrolyte interface and the dramatic decrease in lithium ion diffusivity in the bulk LiFePO4/C material were the key performance limiting factors at low temperature.

AB - The electrochemical performance of LiFePO4/C cathode in a carbonate-based electrolyte (1.0M LiPF6/EC-DMC-PC-FEC) was tested in coin type cells at low temperatures. The discharge capacities of the LiFePO4/C cathode were about 161.6mAh/g (20°C), 141.4mAh/g (-10°C) and 112.9mAh/g (-20°C) at 0.1C charge-discharge rate. The electrode kinetics of LiFePO 4/C cathode was determined at different temperatures using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The analyses demonstrate that the sluggish of charge-transfer reaction on the LiFePO 4/C-electrolyte interface and the dramatic decrease in lithium ion diffusivity in the bulk LiFePO4/C material were the key performance limiting factors at low temperature.

KW - Fluoroethylene carbonate

KW - Lithium ion batteries

KW - Low-temperature electrolyte

UR - https://www.scopus.com/pages/publications/85081812877

M3 - Paper

AN - SCOPUS:85081812877

T2 - 25th World Battery, Hybrid and Fuel Cell Electric Vehicle Symposium and Exhibition: Sustainable Mobility Revolution, EVS 2010

Y2 - 5 November 2010 through 9 November 2010

ER -