Electrochemical investigations of micro-droplets formed on metals during the deliquescence of salt particles in atmosphere

Jibiao Zhang*, Jia Wang, Yanhua Wang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

The formation of micro-droplets, 1-10 μm in diameter, were observed around the edge of main-droplet formed by the deliquescence of salt particles deposited on metals in atmosphere. The characteristics of the formation of micro-droplets were studied in a humidity-controlled chamber. The results showed that oxygen and relative humidity were the key variables for the formation of micro-droplets. Meanwhile, micro-droplets could only appear on the electropositive areas of metal surface based on the potential distributions with the scanning Kelvin probe. The electrochemical polarization results proved that the current established by the potential difference between the central and peripheral area of main-droplet was the true driving force for the formation of micro-droplets.

Original languageEnglish
Pages (from-to)443-448
Number of pages6
JournalElectrochemistry Communications
Volume7
Issue number4
DOIs
Publication statusPublished - Apr 2005
Externally publishedYes

Keywords

  • Atmospheric corrosion
  • Electrochemical polarization
  • Micro-droplets formation
  • Potential distribution

Fingerprint

Dive into the research topics of 'Electrochemical investigations of micro-droplets formed on metals during the deliquescence of salt particles in atmosphere'. Together they form a unique fingerprint.

Cite this