Electrochemical C−H/N−H Activation by Water-Tolerant Cobalt Catalysis at Room Temperature

Cong Tian; Leonardo Massignan; Tjark H. Meyer; Lutz Ackermann

doi:10.1002/anie.201712647

Electrochemical C−H/N−H Activation by Water-Tolerant Cobalt Catalysis at Room Temperature

Cong Tian, Leonardo Massignan, Tjark H. Meyer, Lutz Ackermann^*

^*Corresponding author for this work

University of Göttingen

Research output: Contribution to journal › Article › peer-review

226 Citations (Scopus)

Abstract

Electrochemistry enabled C−H/N−H functionalizations at room temperature by external oxidant-free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C−H activation under exceedingly mild reaction conditions at room temperature in water.

Original language	English
Pages (from-to)	2383-2387
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	9
DOIs	https://doi.org/10.1002/anie.201712647
Publication status	Published - 23 Feb 2018
Externally published	Yes

Keywords

alkynes
cobalt
C−H activation
electrochemistry
synthetic methods

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10.1002/anie.201712647

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abstract = "Electrochemistry enabled C−H/N−H functionalizations at room temperature by external oxidant-free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C−H activation under exceedingly mild reaction conditions at room temperature in water.",

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author = "Cong Tian and Leonardo Massignan and Meyer, \{Tjark H.\} and Lutz Ackermann",

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AU - Tian, Cong

AU - Massignan, Leonardo

AU - Meyer, Tjark H.

AU - Ackermann, Lutz

PY - 2018/2/23

Y1 - 2018/2/23

N2 - Electrochemistry enabled C−H/N−H functionalizations at room temperature by external oxidant-free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C−H activation under exceedingly mild reaction conditions at room temperature in water.

AB - Electrochemistry enabled C−H/N−H functionalizations at room temperature by external oxidant-free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C−H activation under exceedingly mild reaction conditions at room temperature in water.

KW - alkynes

KW - cobalt

KW - C−H activation

KW - electrochemistry

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/85040715304

U2 - 10.1002/anie.201712647

DO - 10.1002/anie.201712647

M3 - Article

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AN - SCOPUS:85040715304

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Electrochemical C−H/N−H Activation by Water-Tolerant Cobalt Catalysis at Room Temperature

Abstract

Keywords

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