Electrocatalytic ethylbenzene valorization using a polyoxometalate@covalent triazine framework with water as the oxygen source

Zhen Li; Chengpeng Liu; Weijie Geng; Jing Dong; Yingnan Chi; Changwen Hu

doi:10.1039/d1cc03186d

Electrocatalytic ethylbenzene valorization using a polyoxometalate@covalent triazine framework with water as the oxygen source

Zhen Li
, Chengpeng Liu
, Weijie Geng
, Jing Dong
, Yingnan Chi^*
, Changwen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Ethylbenzene (EB) oxidation is an important transformation in the chemical industry. Herein, PMo₁₀V₂@CTF, a noble metal free electrocatalyst, was used to promote the oxidative upgrading of EB. Under ambient conditions, 65% of EB was converted to three value-added products using water as the oxygen source yielding a total Faraday efficiency of 90.4%. This excellent performance is ascribed to the homogeneous dispersion of PMo₁₀V₂and its dual role in the electrocatalytic process.

Original language	English
Pages (from-to)	7430-7433
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	60
DOIs	https://doi.org/10.1039/d1cc03186d
Publication status	Published - 4 Aug 2021

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title = "Electrocatalytic ethylbenzene valorization using a polyoxometalate@covalent triazine framework with water as the oxygen source",

abstract = "Ethylbenzene (EB) oxidation is an important transformation in the chemical industry. Herein, PMo10V2@CTF, a noble metal free electrocatalyst, was used to promote the oxidative upgrading of EB. Under ambient conditions, 65\% of EB was converted to three value-added products using water as the oxygen source yielding a total Faraday efficiency of 90.4\%. This excellent performance is ascribed to the homogeneous dispersion of PMo10V2and its dual role in the electrocatalytic process.",

author = "Zhen Li and Chengpeng Liu and Weijie Geng and Jing Dong and Yingnan Chi and Changwen Hu",

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T1 - Electrocatalytic ethylbenzene valorization using a polyoxometalate@covalent triazine framework with water as the oxygen source

AU - Li, Zhen

AU - Liu, Chengpeng

AU - Geng, Weijie

AU - Dong, Jing

AU - Chi, Yingnan

AU - Hu, Changwen

PY - 2021/8/4

Y1 - 2021/8/4

N2 - Ethylbenzene (EB) oxidation is an important transformation in the chemical industry. Herein, PMo10V2@CTF, a noble metal free electrocatalyst, was used to promote the oxidative upgrading of EB. Under ambient conditions, 65% of EB was converted to three value-added products using water as the oxygen source yielding a total Faraday efficiency of 90.4%. This excellent performance is ascribed to the homogeneous dispersion of PMo10V2and its dual role in the electrocatalytic process.

AB - Ethylbenzene (EB) oxidation is an important transformation in the chemical industry. Herein, PMo10V2@CTF, a noble metal free electrocatalyst, was used to promote the oxidative upgrading of EB. Under ambient conditions, 65% of EB was converted to three value-added products using water as the oxygen source yielding a total Faraday efficiency of 90.4%. This excellent performance is ascribed to the homogeneous dispersion of PMo10V2and its dual role in the electrocatalytic process.

UR - https://www.scopus.com/pages/publications/85111420885

U2 - 10.1039/d1cc03186d

DO - 10.1039/d1cc03186d

M3 - Article

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EP - 7433

JO - Chemical Communications

JF - Chemical Communications

IS - 60

ER -

Electrocatalytic ethylbenzene valorization using a polyoxometalate@covalent triazine framework with water as the oxygen source

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