Efficient synthesis of hydroxyl functioned polyesters from natural polyols and sebacic acid

Zhuo Yuan Ning; Qing Shan Zhang; Qin Pei Wu; Yun Zheng Li; Dong Xia Ma; Jia Zhe Chen

doi:10.1016/j.cclet.2010.12.033

Efficient synthesis of hydroxyl functioned polyesters from natural polyols and sebacic acid

Zhuo Yuan Ning
, Qing Shan Zhang
, Qin Pei Wu
, Yun Zheng Li
, Dong Xia Ma
, Jia Zhe Chen

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Amphiphilic hydroxyl functioned polyester (HFP) can be used as compatibilizers for blends of starch and resins. We developed a synthetic method for effective preparation of HFPs. Water was removed by high flow rate N ₂ rather than high vacuum during polycondensation of sebacic acid with xylitol, sorbitol, or mannitol in the presence of dehydrative condensation catalyst and the product is with [η] of 27.2 mL/g, M_n of 1903, M_w of 167,693, T_g of -30.5°C, T_m of 44.0°C. Weight loss is 1.73% under 200°C. The integral distributions of molecular weight are 43.6 wt% and 63.8 wt% over 10,000 and 3000, respectively. The results indicated that higher molecular weight HFP was economically synthesized.

Original language	English
Pages (from-to)	635-638
Number of pages	4
Journal	Chinese Chemical Letters
Volume	22
Issue number	6
DOIs	https://doi.org/10.1016/j.cclet.2010.12.033
Publication status	Published - Jun 2011

Keywords

Biodegradable plastics
Dehydrative condensation catalyst
Hydroxyl functioned polyester
Poly(sorbitol sebacate)

Access to Document

10.1016/j.cclet.2010.12.033

Cite this

@article{86e9c321f69a49e29e1c56a4850f6861,

title = "Efficient synthesis of hydroxyl functioned polyesters from natural polyols and sebacic acid",

abstract = "Amphiphilic hydroxyl functioned polyester (HFP) can be used as compatibilizers for blends of starch and resins. We developed a synthetic method for effective preparation of HFPs. Water was removed by high flow rate N 2 rather than high vacuum during polycondensation of sebacic acid with xylitol, sorbitol, or mannitol in the presence of dehydrative condensation catalyst and the product is with [η] of 27.2 mL/g, Mn of 1903, Mw of 167,693, Tg of -30.5°C, Tm of 44.0°C. Weight loss is 1.73\% under 200°C. The integral distributions of molecular weight are 43.6 wt\% and 63.8 wt\% over 10,000 and 3000, respectively. The results indicated that higher molecular weight HFP was economically synthesized.",

keywords = "Biodegradable plastics, Dehydrative condensation catalyst, Hydroxyl functioned polyester, Poly(sorbitol sebacate)",

author = "Ning, \{Zhuo Yuan\} and Zhang, \{Qing Shan\} and Wu, \{Qin Pei\} and Li, \{Yun Zheng\} and Ma, \{Dong Xia\} and Chen, \{Jia Zhe\}",

year = "2011",

month = jun,

doi = "10.1016/j.cclet.2010.12.033",

language = "English",

volume = "22",

pages = "635--638",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - Efficient synthesis of hydroxyl functioned polyesters from natural polyols and sebacic acid

AU - Ning, Zhuo Yuan

AU - Zhang, Qing Shan

AU - Wu, Qin Pei

AU - Li, Yun Zheng

AU - Ma, Dong Xia

AU - Chen, Jia Zhe

PY - 2011/6

Y1 - 2011/6

N2 - Amphiphilic hydroxyl functioned polyester (HFP) can be used as compatibilizers for blends of starch and resins. We developed a synthetic method for effective preparation of HFPs. Water was removed by high flow rate N 2 rather than high vacuum during polycondensation of sebacic acid with xylitol, sorbitol, or mannitol in the presence of dehydrative condensation catalyst and the product is with [η] of 27.2 mL/g, Mn of 1903, Mw of 167,693, Tg of -30.5°C, Tm of 44.0°C. Weight loss is 1.73% under 200°C. The integral distributions of molecular weight are 43.6 wt% and 63.8 wt% over 10,000 and 3000, respectively. The results indicated that higher molecular weight HFP was economically synthesized.

AB - Amphiphilic hydroxyl functioned polyester (HFP) can be used as compatibilizers for blends of starch and resins. We developed a synthetic method for effective preparation of HFPs. Water was removed by high flow rate N 2 rather than high vacuum during polycondensation of sebacic acid with xylitol, sorbitol, or mannitol in the presence of dehydrative condensation catalyst and the product is with [η] of 27.2 mL/g, Mn of 1903, Mw of 167,693, Tg of -30.5°C, Tm of 44.0°C. Weight loss is 1.73% under 200°C. The integral distributions of molecular weight are 43.6 wt% and 63.8 wt% over 10,000 and 3000, respectively. The results indicated that higher molecular weight HFP was economically synthesized.

KW - Biodegradable plastics

KW - Dehydrative condensation catalyst

KW - Hydroxyl functioned polyester

KW - Poly(sorbitol sebacate)

UR - https://www.scopus.com/pages/publications/79953896533

U2 - 10.1016/j.cclet.2010.12.033

DO - 10.1016/j.cclet.2010.12.033

M3 - Article

AN - SCOPUS:79953896533

SN - 1001-8417

VL - 22

SP - 635

EP - 638

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 6

ER -

Efficient synthesis of hydroxyl functioned polyesters from natural polyols and sebacic acid

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this