Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

Min Jiang; Haijun Yang; Yong Li; Zhiying Jia; Hua Fu

doi:10.1039/c3ra45118f

Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

Min Jiang, Haijun Yang^*, Yong Li, Zhiying Jia, Hua Fu

^*Corresponding author for this work

Tsinghua University

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A novel, simple and efficient ipso-nitration of arylboronic acids with iron nitrate has been developed. The protocol uses readily available arylboronic acids as the starting materials, inexpensive iron nitrate (0.5 equiv.) as the nitro source without addition of an additive, and the corresponding nitroarenes were obtained in good to excellent yields.

Original language	English
Pages (from-to)	25602-25604
Number of pages	3
Journal	RSC Advances
Volume	3
Issue number	48
DOIs	https://doi.org/10.1039/c3ra45118f
Publication status	Published - 28 Dec 2013
Externally published	Yes

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title = "Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source",

abstract = "A novel, simple and efficient ipso-nitration of arylboronic acids with iron nitrate has been developed. The protocol uses readily available arylboronic acids as the starting materials, inexpensive iron nitrate (0.5 equiv.) as the nitro source without addition of an additive, and the corresponding nitroarenes were obtained in good to excellent yields.",

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AU - Jiang, Min

AU - Yang, Haijun

AU - Li, Yong

AU - Jia, Zhiying

AU - Fu, Hua

PY - 2013/12/28

Y1 - 2013/12/28

N2 - A novel, simple and efficient ipso-nitration of arylboronic acids with iron nitrate has been developed. The protocol uses readily available arylboronic acids as the starting materials, inexpensive iron nitrate (0.5 equiv.) as the nitro source without addition of an additive, and the corresponding nitroarenes were obtained in good to excellent yields.

AB - A novel, simple and efficient ipso-nitration of arylboronic acids with iron nitrate has been developed. The protocol uses readily available arylboronic acids as the starting materials, inexpensive iron nitrate (0.5 equiv.) as the nitro source without addition of an additive, and the corresponding nitroarenes were obtained in good to excellent yields.

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U2 - 10.1039/c3ra45118f

DO - 10.1039/c3ra45118f

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SP - 25602

EP - 25604

JO - RSC Advances

JF - RSC Advances

IS - 48

ER -

Efficient ipso-nitration of arylboronic acids with iron nitrate as the nitro source

Abstract

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