Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts

Wei Peng Liu; Ming Lei Yuan; Xiao Hui Yang; Ke Li; Jian Hua Xie; Qi Lin Zhou

doi:10.1039/c5cc00479a

Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts

Wei Peng Liu, Ming Lei Yuan, Xiao Hui Yang, Ke Li, Jian Hua Xie^*, Qi Lin Zhou

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Highly efficient iridium catalyzed asymmetric transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed. By using chiral spiro iridium catalysts (S)-1a a series of alkyl aryl ketones were hydrogenated to chiral alcohols with up to 98% ee.

Original language	English
Pages (from-to)	6123-6125
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	28
DOIs	https://doi.org/10.1039/c5cc00479a
Publication status	Published - 11 Apr 2015
Externally published	Yes

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title = "Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts",

abstract = "Highly efficient iridium catalyzed asymmetric transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed. By using chiral spiro iridium catalysts (S)-1a a series of alkyl aryl ketones were hydrogenated to chiral alcohols with up to 98% ee.",

author = "Liu, {Wei Peng} and Yuan, {Ming Lei} and Yang, {Xiao Hui} and Ke Li and Xie, {Jian Hua} and Zhou, {Qi Lin}",

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doi = "10.1039/c5cc00479a",

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T1 - Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts

AU - Liu, Wei Peng

AU - Yuan, Ming Lei

AU - Yang, Xiao Hui

AU - Li, Ke

AU - Xie, Jian Hua

AU - Zhou, Qi Lin

PY - 2015/4/11

Y1 - 2015/4/11

N2 - Highly efficient iridium catalyzed asymmetric transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed. By using chiral spiro iridium catalysts (S)-1a a series of alkyl aryl ketones were hydrogenated to chiral alcohols with up to 98% ee.

AB - Highly efficient iridium catalyzed asymmetric transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed. By using chiral spiro iridium catalysts (S)-1a a series of alkyl aryl ketones were hydrogenated to chiral alcohols with up to 98% ee.

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U2 - 10.1039/c5cc00479a

DO - 10.1039/c5cc00479a

M3 - Article

C2 - 25743888

AN - SCOPUS:84925612278

SN - 1359-7345

VL - 51

SP - 6123

EP - 6125

JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts

Abstract

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