Effects of Mn(II) on nano silicon@polyaniline electrodes in both half and full cells

Haihui Chen; Hanying Xu; Yingying Zeng; Jinhua Cai; Limin Liu; Tianyi Ma; Fang Wang; Xinping Qiu

doi:10.1002/er.6102

Effects of Mn(II) on nano silicon@polyaniline electrodes in both half and full cells

Haihui Chen^*
, Hanying Xu
, Yingying Zeng^*
, Jinhua Cai
, Limin Liu^*
, Tianyi Ma
, Fang Wang
, Xinping Qiu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In situ growing conductive polyaniline (PANi) has been regarded as a functional binder to enhance the performance of silicon based anodes in half cells, while few papers discussing the influence of Mn²⁺ from cathode on full cells. In this paper, the effects of Mn²⁺ on NSi@PANi electrodes in both half and full cells are investigated, and the mechanism for the fast capacity fade of LiMn₂O₄/NSi@PANi full cell is elucidated. Results reveal that the full cell will significant accelerate the capacity fade of NSi@PANi anode, and the extra consumption of active Li⁺ and electrolytes caused by the deposited Mn²⁺ on silicon anodes in lithium manganate (LMO)/NSi@PANi full cells is confirmed as the main reason of the capacity fade and lower coulombic efficiency for the excessive growth of solid electrolyte interphase.

Original language	English
Pages (from-to)	4357-4369
Number of pages	13
Journal	International Journal of Energy Research
Volume	45
Issue number	3
DOIs	https://doi.org/10.1002/er.6102
Publication status	Published - 10 Mar 2021
Externally published	Yes

Keywords

LMO full cell
Mn ion
capacity fade
lithium-ion battery
polyaniline
silicon electrode

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/er.6102

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@article{f9c5c476db2443d9addbf613ecb2fb1c,

title = "Effects of Mn(II) on nano silicon@polyaniline electrodes in both half and full cells",

abstract = "In situ growing conductive polyaniline (PANi) has been regarded as a functional binder to enhance the performance of silicon based anodes in half cells, while few papers discussing the influence of Mn2+ from cathode on full cells. In this paper, the effects of Mn2+ on NSi@PANi electrodes in both half and full cells are investigated, and the mechanism for the fast capacity fade of LiMn2O4/NSi@PANi full cell is elucidated. Results reveal that the full cell will significant accelerate the capacity fade of NSi@PANi anode, and the extra consumption of active Li+ and electrolytes caused by the deposited Mn2+ on silicon anodes in lithium manganate (LMO)/NSi@PANi full cells is confirmed as the main reason of the capacity fade and lower coulombic efficiency for the excessive growth of solid electrolyte interphase.",

keywords = "LMO full cell, Mn ion, capacity fade, lithium-ion battery, polyaniline, silicon electrode",

author = "Haihui Chen and Hanying Xu and Yingying Zeng and Jinhua Cai and Limin Liu and Tianyi Ma and Fang Wang and Xinping Qiu",

note = "Publisher Copyright: {\textcopyright} 2020 John Wiley \& Sons Ltd",

year = "2021",

month = mar,

day = "10",

doi = "10.1002/er.6102",

language = "English",

volume = "45",

pages = "4357--4369",

journal = "International Journal of Energy Research",

issn = "0363-907X",

publisher = "John Wiley and Sons Ltd",

number = "3",

}

TY - JOUR

T1 - Effects of Mn(II) on nano silicon@polyaniline electrodes in both half and full cells

AU - Chen, Haihui

AU - Xu, Hanying

AU - Zeng, Yingying

AU - Cai, Jinhua

AU - Liu, Limin

AU - Ma, Tianyi

AU - Wang, Fang

AU - Qiu, Xinping

PY - 2021/3/10

Y1 - 2021/3/10

N2 - In situ growing conductive polyaniline (PANi) has been regarded as a functional binder to enhance the performance of silicon based anodes in half cells, while few papers discussing the influence of Mn2+ from cathode on full cells. In this paper, the effects of Mn2+ on NSi@PANi electrodes in both half and full cells are investigated, and the mechanism for the fast capacity fade of LiMn2O4/NSi@PANi full cell is elucidated. Results reveal that the full cell will significant accelerate the capacity fade of NSi@PANi anode, and the extra consumption of active Li+ and electrolytes caused by the deposited Mn2+ on silicon anodes in lithium manganate (LMO)/NSi@PANi full cells is confirmed as the main reason of the capacity fade and lower coulombic efficiency for the excessive growth of solid electrolyte interphase.

AB - In situ growing conductive polyaniline (PANi) has been regarded as a functional binder to enhance the performance of silicon based anodes in half cells, while few papers discussing the influence of Mn2+ from cathode on full cells. In this paper, the effects of Mn2+ on NSi@PANi electrodes in both half and full cells are investigated, and the mechanism for the fast capacity fade of LiMn2O4/NSi@PANi full cell is elucidated. Results reveal that the full cell will significant accelerate the capacity fade of NSi@PANi anode, and the extra consumption of active Li+ and electrolytes caused by the deposited Mn2+ on silicon anodes in lithium manganate (LMO)/NSi@PANi full cells is confirmed as the main reason of the capacity fade and lower coulombic efficiency for the excessive growth of solid electrolyte interphase.

KW - LMO full cell

KW - Mn ion

KW - capacity fade

KW - lithium-ion battery

KW - polyaniline

KW - silicon electrode

UR - https://www.scopus.com/pages/publications/85097385949

U2 - 10.1002/er.6102

DO - 10.1002/er.6102

M3 - Article

AN - SCOPUS:85097385949

SN - 0363-907X

VL - 45

SP - 4357

EP - 4369

JO - International Journal of Energy Research

JF - International Journal of Energy Research

IS - 3

ER -

Effects of Mn(II) on nano silicon@polyaniline electrodes in both half and full cells

Abstract

Keywords

UN SDGs

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