Effect of Ti on the stability of phases in the (1 - X)Pb(Mg 1/3Nb 2/3)O 3-xPbTiO 3 solid solution

J. B. Li; G. H. Rao; G. Y. Liu; J. R. Chen; J. K. Liang

doi:10.1080/00150190490903784

Effect of Ti on the stability of phases in the (1 - X)Pb(Mg _1/3Nb _2/3)O ₃-xPbTiO ₃ solid solution

J. B. Li^*, G. H. Rao, G. Y. Liu, J. R. Chen, J. K. Liang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Occurrence of the M_B-type monoclinic phase induced by the lattice distortion of the rhombohedral structure was evidenced by means of high-resolution x-ray powder diffraction, simplified integrate-breadth analysis and Rietveld refinement in the (1-x)- Pb(Mg_1/3Nb_2/3)O ₃-xPbTiO₃(PMN-xPT) ceramics with 15%≤x≤30%. The obvious distortion of lattice along [00h]_Cwas observed in the composition range 23%≤x≤30%, and increased with the Ti content. Rietveld refinements indicate that the M_B-type monoclinic phase exists in the composition range 23%≤x≤25%, and coexists, as a majority phase, with the M_C-type monoclinic phase for 26%≤x≤30%. The rhombohedral (R) phase is stable in the composition range of 15%≤x < 23%. The effect of Ti on the lattice distortion and phase stability in the PMN-PT solid solution is discussed based on the model of competition between rhombohedral and tetragonal polar orders.

Original language	English
Pages (from-to)	71-80
Number of pages	10
Journal	Ferroelectrics
Volume	313
DOIs	https://doi.org/10.1080/00150190490903784
Publication status	Published - 2005
Externally published	Yes

Keywords

Lattice distortion
Pb(Mg Nb )O -PbTiO
Phase transition
X-ray diffraction

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@article{21ebf99c2c40404a9013e7fc4aa60de3,

title = "Effect of Ti on the stability of phases in the (1 - X)Pb(Mg 1/3Nb 2/3)O 3-xPbTiO 3 solid solution",

abstract = "Occurrence of the MB-type monoclinic phase induced by the lattice distortion of the rhombohedral structure was evidenced by means of high-resolution x-ray powder diffraction, simplified integrate-breadth analysis and Rietveld refinement in the (1-x)- Pb(Mg1/3Nb2/3)O 3-xPbTiO3(PMN-xPT) ceramics with 15\%≤x≤30\%. The obvious distortion of lattice along [00h]Cwas observed in the composition range 23\%≤x≤30\%, and increased with the Ti content. Rietveld refinements indicate that the MB-type monoclinic phase exists in the composition range 23\%≤x≤25\%, and coexists, as a majority phase, with the MC-type monoclinic phase for 26\%≤x≤30\%. The rhombohedral (R) phase is stable in the composition range of 15\%≤x < 23\%. The effect of Ti on the lattice distortion and phase stability in the PMN-PT solid solution is discussed based on the model of competition between rhombohedral and tetragonal polar orders.",

keywords = "Lattice distortion, Pb(Mg Nb )O -PbTiO, Phase transition, X-ray diffraction",

author = "Li, \{J. B.\} and Rao, \{G. H.\} and Liu, \{G. Y.\} and Chen, \{J. R.\} and Liang, \{J. K.\}",

year = "2005",

doi = "10.1080/00150190490903784",

language = "English",

volume = "313",

pages = "71--80",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Effect of Ti on the stability of phases in the (1 - X)Pb(Mg 1/3Nb 2/3)O 3-xPbTiO 3 solid solution

AU - Li, J. B.

AU - Rao, G. H.

AU - Liu, G. Y.

AU - Chen, J. R.

AU - Liang, J. K.

PY - 2005

Y1 - 2005

N2 - Occurrence of the MB-type monoclinic phase induced by the lattice distortion of the rhombohedral structure was evidenced by means of high-resolution x-ray powder diffraction, simplified integrate-breadth analysis and Rietveld refinement in the (1-x)- Pb(Mg1/3Nb2/3)O 3-xPbTiO3(PMN-xPT) ceramics with 15%≤x≤30%. The obvious distortion of lattice along [00h]Cwas observed in the composition range 23%≤x≤30%, and increased with the Ti content. Rietveld refinements indicate that the MB-type monoclinic phase exists in the composition range 23%≤x≤25%, and coexists, as a majority phase, with the MC-type monoclinic phase for 26%≤x≤30%. The rhombohedral (R) phase is stable in the composition range of 15%≤x < 23%. The effect of Ti on the lattice distortion and phase stability in the PMN-PT solid solution is discussed based on the model of competition between rhombohedral and tetragonal polar orders.

AB - Occurrence of the MB-type monoclinic phase induced by the lattice distortion of the rhombohedral structure was evidenced by means of high-resolution x-ray powder diffraction, simplified integrate-breadth analysis and Rietveld refinement in the (1-x)- Pb(Mg1/3Nb2/3)O 3-xPbTiO3(PMN-xPT) ceramics with 15%≤x≤30%. The obvious distortion of lattice along [00h]Cwas observed in the composition range 23%≤x≤30%, and increased with the Ti content. Rietveld refinements indicate that the MB-type monoclinic phase exists in the composition range 23%≤x≤25%, and coexists, as a majority phase, with the MC-type monoclinic phase for 26%≤x≤30%. The rhombohedral (R) phase is stable in the composition range of 15%≤x < 23%. The effect of Ti on the lattice distortion and phase stability in the PMN-PT solid solution is discussed based on the model of competition between rhombohedral and tetragonal polar orders.

KW - Lattice distortion

KW - Pb(Mg Nb )O -PbTiO

KW - Phase transition

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=33845606269&partnerID=8YFLogxK

U2 - 10.1080/00150190490903784

DO - 10.1080/00150190490903784

M3 - Article

AN - SCOPUS:33845606269

SN - 0015-0193

VL - 313

SP - 71

EP - 80

JO - Ferroelectrics

JF - Ferroelectrics

ER -

Effect of Ti on the stability of phases in the (1 - X)Pb(Mg _1/3Nb _2/3)O ₃-xPbTiO ₃ solid solution

Abstract

Keywords

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