Effect of the polycarbosilane structure on its final ceramic yield

Houbu Li; Litong Zhang; Laifei Cheng; Yiguang Wang; Zhaoju Yu; Muhe Huang; Huibin Tu; Haiping Xia

doi:10.1016/j.jeurceramsoc.2007.07.020

Effect of the polycarbosilane structure on its final ceramic yield

Houbu Li
, Litong Zhang
, Laifei Cheng
, Yiguang Wang^*
, Zhaoju Yu
, Muhe Huang
, Huibin Tu
, Haiping Xia

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

124 Citations (Scopus)

Abstract

The ceramic yield of a new polycarbosilane is discussed based on its structure, including vinyl functionality, branched structure, as well as polymer molecular weight. The cross-linking behavior of this polymer is studied up to 400 °C. According to the cross-linking mechanism, the optimized heat-treatment conditions can be obtained for a high ceramic yield. The product pyrolysized at 1400 °C has a composition close to 1.1:1 Si:C with a ceramic yield of about 70%.

Original language	English
Pages (from-to)	887-891
Number of pages	5
Journal	Journal of the European Ceramic Society
Volume	28
Issue number	4
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2007.07.020
Publication status	Published - 2008
Externally published	Yes

Keywords

Ceramic yield
Cross-linking
Polycarbosilane structure
Precursors-organic
SiC

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10.1016/j.jeurceramsoc.2007.07.020

Cite this

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title = "Effect of the polycarbosilane structure on its final ceramic yield",

abstract = "The ceramic yield of a new polycarbosilane is discussed based on its structure, including vinyl functionality, branched structure, as well as polymer molecular weight. The cross-linking behavior of this polymer is studied up to 400 °C. According to the cross-linking mechanism, the optimized heat-treatment conditions can be obtained for a high ceramic yield. The product pyrolysized at 1400 °C has a composition close to 1.1:1 Si:C with a ceramic yield of about 70\%.",

keywords = "Ceramic yield, Cross-linking, Polycarbosilane structure, Precursors-organic, SiC",

author = "Houbu Li and Litong Zhang and Laifei Cheng and Yiguang Wang and Zhaoju Yu and Muhe Huang and Huibin Tu and Haiping Xia",

year = "2008",

doi = "10.1016/j.jeurceramsoc.2007.07.020",

language = "English",

volume = "28",

pages = "887--891",

journal = "Journal of the European Ceramic Society",

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}

TY - JOUR

T1 - Effect of the polycarbosilane structure on its final ceramic yield

AU - Li, Houbu

AU - Zhang, Litong

AU - Cheng, Laifei

AU - Wang, Yiguang

AU - Yu, Zhaoju

AU - Huang, Muhe

AU - Tu, Huibin

AU - Xia, Haiping

PY - 2008

Y1 - 2008

N2 - The ceramic yield of a new polycarbosilane is discussed based on its structure, including vinyl functionality, branched structure, as well as polymer molecular weight. The cross-linking behavior of this polymer is studied up to 400 °C. According to the cross-linking mechanism, the optimized heat-treatment conditions can be obtained for a high ceramic yield. The product pyrolysized at 1400 °C has a composition close to 1.1:1 Si:C with a ceramic yield of about 70%.

AB - The ceramic yield of a new polycarbosilane is discussed based on its structure, including vinyl functionality, branched structure, as well as polymer molecular weight. The cross-linking behavior of this polymer is studied up to 400 °C. According to the cross-linking mechanism, the optimized heat-treatment conditions can be obtained for a high ceramic yield. The product pyrolysized at 1400 °C has a composition close to 1.1:1 Si:C with a ceramic yield of about 70%.

KW - Ceramic yield

KW - Cross-linking

KW - Polycarbosilane structure

KW - Precursors-organic

KW - SiC

UR - https://www.scopus.com/pages/publications/37549007972

U2 - 10.1016/j.jeurceramsoc.2007.07.020

DO - 10.1016/j.jeurceramsoc.2007.07.020

M3 - Article

AN - SCOPUS:37549007972

SN - 0955-2219

VL - 28

SP - 887

EP - 891

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 4

ER -

Effect of the polycarbosilane structure on its final ceramic yield

Abstract

Keywords

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