Effect of fluoropolymer content on thermal and combustion performance of direct writing high-solid nanothermite composite

The addition of fluoropolymers can improve the reactivity of Al and enhance the combustion performance of thermites, which has attracted great interest. Also, direct writing 3D printing technology for the preparation of energetic materials is an innovative process that can meet a variety of complex requirements. In this study, soluble Viton F2311 was used as a binder, and F2311/Al/CuO (FMICs) nanocomposites were prepared by direct writing. The components of FMICs were evenly distributed without obvious agglomeration. The thermal and combustion properties of FMICs with different mass fractions of F2311 were systematically studied. As the F2311 content increases, the thermite reaction of FMICs is advanced and the system has a higher exothermic and combustion rate. The F2311 content had little effect on the combustion flame temperature of FMICs, all of which were above 2400 K. Compared with PTFE and new fluoropolymers/nanothermites, F2311/nanothermites shows better processability and reaction properties and probably has promising applications.