Abstract
A single-phase Yb2Si2O7 coating was deposited on SiCf/SiC composites with a silicon bond coat using air plasma spraying. The hot corrosion behavior of Yb2Si2O7-coated SiCf/SiC was investigated in a coupling environment consisting of water vapor and calcium–magnesium–aluminum–silicate (CMAS) with static oxidation at 1350 °C. The evolution of the phase and cross-sectional morphology of the samples was characterized using X-ray diffraction and scanning electron microscopy. The results indicate that thermal stress generated by the growth of the thermally grown oxide (TGO) layer leads to the fractures at the TGO–Yb2Si2O7 interface in samples loaded with low CMAS concentration. In samples with high CMAS concentration, excess CMAS reacts with the TGO layer, destroying its structure and accelerating the oxidation of the Si bond coat. Cracks bifurcate within the TGO layer, extend along the TGO interface, and ultimately penetrate the interior of the TGO layer. The concentration of CMAS influences the crack propagation mode within the TGO layer and alters the failure behavior of the coating.
Original language | English |
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Article number | 117233 |
Journal | Journal of the European Ceramic Society |
Volume | 45 |
Issue number | 6 |
DOIs | |
Publication status | Published - Jun 2025 |
Keywords
- Ceramic matrix composites
- CMAS corrosion
- Crack propagation
- Environmental barrier coatings
- Oxidation