Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

Lin Ge Ma; Da Ming Du; Jia Xi Xu

Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

Lin Ge Ma^*
, Da Ming Du
, Jia Xi Xu

^*Corresponding author for this work

Peking University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.

Original language	English
Pages (from-to)	568-572
Number of pages	5
Journal	Chinese Journal of Organic Chemistry
Volume	26
Issue number	4
Publication status	Published - Apr 2006
Externally published	Yes

Keywords

Asymmetric aziridination
Bisoxazoline
Chelate size
Enantioselectivity
Ligand

Cite this

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title = "Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination",

abstract = "Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.",

keywords = "Asymmetric aziridination, Bisoxazoline, Chelate size, Enantioselectivity, Ligand",

author = "Ma, \{Lin Ge\} and Du, \{Da Ming\} and Xu, \{Jia Xi\}",

year = "2006",

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language = "English",

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pages = "568--572",

journal = "Chinese Journal of Organic Chemistry",

issn = "0253-2786",

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T1 - Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

AU - Ma, Lin Ge

AU - Du, Da Ming

AU - Xu, Jia Xi

PY - 2006/4

Y1 - 2006/4

N2 - Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.

AB - Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized. The effect of their chelate sizes on the enantioselectivity was investigated in the asymmetric aziridination. The results indicate that tuning chelate size can not only change the enantioselectivity, but also change the enantiofacial selectivity completely.

KW - Asymmetric aziridination

KW - Bisoxazoline

KW - Chelate size

KW - Enantioselectivity

KW - Ligand

UR - https://www.scopus.com/pages/publications/33744995559

M3 - Article

AN - SCOPUS:33744995559

SN - 0253-2786

VL - 26

SP - 568

EP - 572

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 4

ER -

Effect of chelate size of bisoxazolines on the enantioselectivity of the asymmetric aziridination

Abstract

Keywords

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