Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Jia Sheng Pan; Rui Zhang; Shuang Shuang Ma; Li Jun Han; Bao Hua Xu

doi:10.1002/slct.202002795

Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Jia Sheng Pan
, Rui Zhang^*
, Shuang Shuang Ma
, Li Jun Han
, Bao Hua Xu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H₂ and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

Original language	English
Pages (from-to)	10933-10938
Number of pages	6
Journal	ChemistrySelect
Volume	5
Issue number	35
DOIs	https://doi.org/10.1002/slct.202002795
Publication status	Published - 22 Sept 2020
Externally published	Yes

Keywords

Homogeneous catalysis
Primary amines
Reductive amination
Ruthenium

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10.1002/slct.202002795

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title = "Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines",

abstract = "An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.",

keywords = "Homogeneous catalysis, Primary amines, Reductive amination, Ruthenium",

author = "Pan, \{Jia Sheng\} and Rui Zhang and Ma, \{Shuang Shuang\} and Han, \{Li Jun\} and Xu, \{Bao Hua\}",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH",

year = "2020",

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doi = "10.1002/slct.202002795",

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journal = "ChemistrySelect",

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T1 - Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

AU - Pan, Jia Sheng

AU - Zhang, Rui

AU - Ma, Shuang Shuang

AU - Han, Li Jun

AU - Xu, Bao Hua

PY - 2020/9/22

Y1 - 2020/9/22

N2 - An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

AB - An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

KW - Homogeneous catalysis

KW - Primary amines

KW - Reductive amination

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/85091290866

U2 - 10.1002/slct.202002795

DO - 10.1002/slct.202002795

M3 - Article

AN - SCOPUS:85091290866

SN - 2365-6549

VL - 5

SP - 10933

EP - 10938

JO - ChemistrySelect

JF - ChemistrySelect

IS - 35

ER -

Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Abstract

Keywords

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