Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)2}2(μ-S)2] building blocks

Wenjian Zhang; Xintao Wu; Biao Wu; Shuyan Yu; Gabriella Santoni; Dieter Rehder

doi:10.1021/ic020510p

Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)₂}₂(μ-S)₂] building blocks

Wenjian Zhang, Xintao Wu, Biao Wu, Shuyan Yu, Gabriella Santoni, Dieter Rehder^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The dimeric W^V complex [Et₄N]₄[syn-{O=W(NCS)₃}₂ (μ-S)₂], 1, prepared from [Et₄N]₂[WS₄], SCN^-, and Cd²⁺, shows interesting reactivity patterns in that the thiocyanate trans to the oxo group can in part be replaced, initiated by Mn²⁺, by dimethylformamide (DMF) to form [Et₄N]_2.5[{O=W(NCS)_2.25 (DMF)_1.25}₂(μ-S)₂], 2. With Ag⁺, 1 undergoes partial replacement of SCN^- by DMF and coordinates to the silver ions to generate {[Et₄N]_2.5[{W₂O₂ (NCS)₂(μ-S)₂}(μ-NCS)₂(DMF) {Ag_0.5(SCN)}]}_n, 3. Compound 3 constitutes a polymeric double-stranded chain, with normal bonding interactions [via W-(μ-NCS)-Ag] between the two strands, and moderate intrastrand [W-(μ-NCS)···Ag] bonding. The crystal and molecular structures of the three compounds are described.

Original language	English
Pages (from-to)	1130-1134
Number of pages	5
Journal	Inorganic Chemistry
Volume	42
Issue number	4
DOIs	https://doi.org/10.1021/ic020510p
Publication status	Published - 24 Feb 2003
Externally published	Yes

Access to Document

10.1021/ic020510p

Cite this

@article{c79db14e2ff6464faa58b902bcce8b10,

title = "Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)2}2(μ-S)2] building blocks",

abstract = "The dimeric WV complex [Et4N]4[syn-{O=W(NCS)3}2 (μ-S)2], 1, prepared from [Et4N]2[WS4], SCN-, and Cd2+, shows interesting reactivity patterns in that the thiocyanate trans to the oxo group can in part be replaced, initiated by Mn2+, by dimethylformamide (DMF) to form [Et4N]2.5[{O=W(NCS)2.25 (DMF)1.25}2(μ-S)2], 2. With Ag+, 1 undergoes partial replacement of SCN- by DMF and coordinates to the silver ions to generate {[Et4N]2.5[{W2O2 (NCS)2(μ-S)2}(μ-NCS)2(DMF) {Ag0.5(SCN)}]}n, 3. Compound 3 constitutes a polymeric double-stranded chain, with normal bonding interactions [via W-(μ-NCS)-Ag] between the two strands, and moderate intrastrand [W-(μ-NCS)···Ag] bonding. The crystal and molecular structures of the three compounds are described.",

author = "Wenjian Zhang and Xintao Wu and Biao Wu and Shuyan Yu and Gabriella Santoni and Dieter Rehder",

year = "2003",

month = feb,

day = "24",

doi = "10.1021/ic020510p",

language = "English",

volume = "42",

pages = "1130--1134",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)2}2(μ-S)2] building blocks

AU - Zhang, Wenjian

AU - Wu, Xintao

AU - Wu, Biao

AU - Yu, Shuyan

AU - Santoni, Gabriella

AU - Rehder, Dieter

PY - 2003/2/24

Y1 - 2003/2/24

N2 - The dimeric WV complex [Et4N]4[syn-{O=W(NCS)3}2 (μ-S)2], 1, prepared from [Et4N]2[WS4], SCN-, and Cd2+, shows interesting reactivity patterns in that the thiocyanate trans to the oxo group can in part be replaced, initiated by Mn2+, by dimethylformamide (DMF) to form [Et4N]2.5[{O=W(NCS)2.25 (DMF)1.25}2(μ-S)2], 2. With Ag+, 1 undergoes partial replacement of SCN- by DMF and coordinates to the silver ions to generate {[Et4N]2.5[{W2O2 (NCS)2(μ-S)2}(μ-NCS)2(DMF) {Ag0.5(SCN)}]}n, 3. Compound 3 constitutes a polymeric double-stranded chain, with normal bonding interactions [via W-(μ-NCS)-Ag] between the two strands, and moderate intrastrand [W-(μ-NCS)···Ag] bonding. The crystal and molecular structures of the three compounds are described.

AB - The dimeric WV complex [Et4N]4[syn-{O=W(NCS)3}2 (μ-S)2], 1, prepared from [Et4N]2[WS4], SCN-, and Cd2+, shows interesting reactivity patterns in that the thiocyanate trans to the oxo group can in part be replaced, initiated by Mn2+, by dimethylformamide (DMF) to form [Et4N]2.5[{O=W(NCS)2.25 (DMF)1.25}2(μ-S)2], 2. With Ag+, 1 undergoes partial replacement of SCN- by DMF and coordinates to the silver ions to generate {[Et4N]2.5[{W2O2 (NCS)2(μ-S)2}(μ-NCS)2(DMF) {Ag0.5(SCN)}]}n, 3. Compound 3 constitutes a polymeric double-stranded chain, with normal bonding interactions [via W-(μ-NCS)-Ag] between the two strands, and moderate intrastrand [W-(μ-NCS)···Ag] bonding. The crystal and molecular structures of the three compounds are described.

UR - http://www.scopus.com/inward/record.url?scp=0037463645&partnerID=8YFLogxK

U2 - 10.1021/ic020510p

DO - 10.1021/ic020510p

M3 - Article

C2 - 12588148

AN - SCOPUS:0037463645

SN - 0020-1669

VL - 42

SP - 1130

EP - 1134

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)₂}₂(μ-S)₂] building blocks

Abstract

Access to Document

Other files and links

Fingerprint

Cite this