Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex

Xiao Peng Sun; Zheng Tang; Jiajia Li; Pengtao Ma; Zi Shuo Yao; Jingping Wang; Jingyang Niu; Jun Tao

doi:10.1021/acs.inorgchem.1c03898

Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex

Xiao Peng Sun^*
, Zheng Tang
, Jiajia Li
, Pengtao Ma
, Zi Shuo Yao
, Jingping Wang
, Jingyang Niu^*
, Jun Tao^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests.

Original language	English
Pages (from-to)	4240-4245
Number of pages	6
Journal	Inorganic Chemistry
Volume	61
Issue number	10
DOIs	https://doi.org/10.1021/acs.inorgchem.1c03898
Publication status	Published - 14 Mar 2022

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10.1021/acs.inorgchem.1c03898

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title = "Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex",

abstract = "Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests.",

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AU - Sun, Xiao Peng

AU - Tang, Zheng

AU - Li, Jiajia

AU - Ma, Pengtao

AU - Yao, Zi Shuo

AU - Wang, Jingping

AU - Niu, Jingyang

AU - Tao, Jun

PY - 2022/3/14

Y1 - 2022/3/14

N2 - Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests.

AB - Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests.

UR - https://www.scopus.com/pages/publications/85126313973

U2 - 10.1021/acs.inorgchem.1c03898

DO - 10.1021/acs.inorgchem.1c03898

M3 - Article

C2 - 35234459

AN - SCOPUS:85126313973

SN - 0020-1669

VL - 61

SP - 4240

EP - 4245

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 10

ER -

Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex

Abstract

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