Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene

Vasile Lozan; Paul Gerhard Lassahn; Cungen Zhang; Biao Wu; Christoph Janiak; Gerd Rheinwald; Heinrich Lang

doi:10.1515/znb-2003-1202

Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene

Vasile Lozan, Paul Gerhard Lassahn, Cungen Zhang, Biao Wu, Christoph Janiak^*, Gerd Rheinwald, Heinrich Lang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

Dinuclear nickel(II) and palladium(II) complexes with Schiff-base ligands (derived form salicylaldehyde condensed with 2-amino-1-alcohols or from 2-hydroxy-5-methylisophthaldialdehyde and pyridine-2-carboxaldehyde condensed with semicarbazide, thiosemicarbazide, carbonodihydrazide, or thiocarbonodihydrazide) can be activated with the co-catalysts methylalumoxane (MAO) or tris(pentafluorophenyl)borane/triethylaluminium, B (C₆F ₅)3/AlEt₃ for the vinyl/addition polymerization of norbornene to reach activities of up to 2.4·10⁷ g _polymer/mol(metal)·h (molar ratios metal:Al_MAO = 1:100, metal:borane:AlEt₃ = 1:9:10). Polymer characterization by GPC gave molar mass distributions of M_w/M_n ≈ 2, thereby indicating a coordination polymerization with a single-site character of the active species.

Original language	English
Pages (from-to)	1152-1164
Number of pages	13
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	58
Issue number	12
DOIs	https://doi.org/10.1515/znb-2003-1202
Publication status	Published - Dec 2003
Externally published	Yes

Keywords

Co-Catalyst
Nickel
Norbornene
Palladium
Polymerization

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10.1515/znb-2003-1202

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Lozan, V., Lassahn, P. G., Zhang, C., Wu, B., Janiak, C., Rheinwald, G., & Lang, H. (2003). Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 58(12), 1152-1164. https://doi.org/10.1515/znb-2003-1202

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title = "Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene",

abstract = "Dinuclear nickel(II) and palladium(II) complexes with Schiff-base ligands (derived form salicylaldehyde condensed with 2-amino-1-alcohols or from 2-hydroxy-5-methylisophthaldialdehyde and pyridine-2-carboxaldehyde condensed with semicarbazide, thiosemicarbazide, carbonodihydrazide, or thiocarbonodihydrazide) can be activated with the co-catalysts methylalumoxane (MAO) or tris(pentafluorophenyl)borane/triethylaluminium, B (C6F 5)3/AlEt3 for the vinyl/addition polymerization of norbornene to reach activities of up to 2.4·107 g polymer/mol(metal)·h (molar ratios metal:AlMAO = 1:100, metal:borane:AlEt3 = 1:9:10). Polymer characterization by GPC gave molar mass distributions of Mw/Mn ≈ 2, thereby indicating a coordination polymerization with a single-site character of the active species.",

keywords = "Co-Catalyst, Nickel, Norbornene, Palladium, Polymerization",

author = "Vasile Lozan and Lassahn, {Paul Gerhard} and Cungen Zhang and Biao Wu and Christoph Janiak and Gerd Rheinwald and Heinrich Lang",

year = "2003",

month = dec,

doi = "10.1515/znb-2003-1202",

language = "English",

volume = "58",

pages = "1152--1164",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

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Lozan, V, Lassahn, PG, Zhang, C, Wu, B, Janiak, C, Rheinwald, G & Lang, H 2003, 'Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene', Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 58, no. 12, pp. 1152-1164. https://doi.org/10.1515/znb-2003-1202

Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene. / Lozan, Vasile; Lassahn, Paul Gerhard; Zhang, Cungen et al.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 58, No. 12, 12.2003, p. 1152-1164.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene

AU - Lozan, Vasile

AU - Lassahn, Paul Gerhard

AU - Zhang, Cungen

AU - Wu, Biao

AU - Janiak, Christoph

AU - Rheinwald, Gerd

AU - Lang, Heinrich

PY - 2003/12

Y1 - 2003/12

N2 - Dinuclear nickel(II) and palladium(II) complexes with Schiff-base ligands (derived form salicylaldehyde condensed with 2-amino-1-alcohols or from 2-hydroxy-5-methylisophthaldialdehyde and pyridine-2-carboxaldehyde condensed with semicarbazide, thiosemicarbazide, carbonodihydrazide, or thiocarbonodihydrazide) can be activated with the co-catalysts methylalumoxane (MAO) or tris(pentafluorophenyl)borane/triethylaluminium, B (C6F 5)3/AlEt3 for the vinyl/addition polymerization of norbornene to reach activities of up to 2.4·107 g polymer/mol(metal)·h (molar ratios metal:AlMAO = 1:100, metal:borane:AlEt3 = 1:9:10). Polymer characterization by GPC gave molar mass distributions of Mw/Mn ≈ 2, thereby indicating a coordination polymerization with a single-site character of the active species.

AB - Dinuclear nickel(II) and palladium(II) complexes with Schiff-base ligands (derived form salicylaldehyde condensed with 2-amino-1-alcohols or from 2-hydroxy-5-methylisophthaldialdehyde and pyridine-2-carboxaldehyde condensed with semicarbazide, thiosemicarbazide, carbonodihydrazide, or thiocarbonodihydrazide) can be activated with the co-catalysts methylalumoxane (MAO) or tris(pentafluorophenyl)borane/triethylaluminium, B (C6F 5)3/AlEt3 for the vinyl/addition polymerization of norbornene to reach activities of up to 2.4·107 g polymer/mol(metal)·h (molar ratios metal:AlMAO = 1:100, metal:borane:AlEt3 = 1:9:10). Polymer characterization by GPC gave molar mass distributions of Mw/Mn ≈ 2, thereby indicating a coordination polymerization with a single-site character of the active species.

KW - Co-Catalyst

KW - Nickel

KW - Norbornene

KW - Palladium

KW - Polymerization

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U2 - 10.1515/znb-2003-1202

DO - 10.1515/znb-2003-1202

M3 - Article

AN - SCOPUS:0842330475

SN - 0932-0776

VL - 58

SP - 1152

EP - 1164

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 12

ER -

Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene

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