Diaquabis(4,4′-bipyridine N,N′-dioxide-kO)-bis(dicyanamido) cadmium(II)

Yanqing Xu; Daqiang Yuan; Ying Xu; Wenhua Bi; Youfu Zhou; Maochun Hong

doi:10.1107/S1600536804010281

Diaquabis(4,4′-bipyridine N,N′-dioxide-kO)-bis(dicyanamido) cadmium(II)

Yanqing Xu
, Daqiang Yuan
, Ying Xu
, Wenhua Bi
, Youfu Zhou
, Maochun Hong^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The structure of the title compound, [Cd(dca)₂(bpno) ₂(H₂O)₂], contains a Cd atom coordinated by bpno (4,4′-bipyridine N,N′-dioxide, C₁₀H ₈N₂O₂), dca [dca is dicyanamide, N(CN) ₂^-] and two water molecules. The central Cd^II ion is located at an inversion center, coordinated by two N atoms from dca, two O atoms from bpno and two O atoms from water molecules, in an approximately octahedral geometry. This discrete structure is further extended to form a two-dimensional layer structure involving weak hydrogen bonds. The compound is isostructural with its cobalt analog [Aneta, Zdirad, Augustin, Jiri & Marius (2003). Polyhedron, 22, 789-794].

Original language	English
Pages (from-to)	m713-m714
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	6
DOIs	https://doi.org/10.1107/S1600536804010281
Publication status	Published - Jun 2004
Externally published	Yes

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title = "Diaquabis(4,4′-bipyridine N,N′-dioxide-kO)-bis(dicyanamido) cadmium(II)",

abstract = "The structure of the title compound, [Cd(dca)2(bpno) 2(H2O)2], contains a Cd atom coordinated by bpno (4,4′-bipyridine N,N′-dioxide, C10H 8N2O2), dca [dca is dicyanamide, N(CN) 2-] and two water molecules. The central CdII ion is located at an inversion center, coordinated by two N atoms from dca, two O atoms from bpno and two O atoms from water molecules, in an approximately octahedral geometry. This discrete structure is further extended to form a two-dimensional layer structure involving weak hydrogen bonds. The compound is isostructural with its cobalt analog [Aneta, Zdirad, Augustin, Jiri \& Marius (2003). Polyhedron, 22, 789-794].",

author = "Yanqing Xu and Daqiang Yuan and Ying Xu and Wenhua Bi and Youfu Zhou and Maochun Hong",

year = "2004",

month = jun,

doi = "10.1107/S1600536804010281",

language = "English",

volume = "60",

pages = "m713--m714",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - Diaquabis(4,4′-bipyridine N,N′-dioxide-kO)-bis(dicyanamido) cadmium(II)

AU - Xu, Yanqing

AU - Yuan, Daqiang

AU - Xu, Ying

AU - Bi, Wenhua

AU - Zhou, Youfu

AU - Hong, Maochun

PY - 2004/6

Y1 - 2004/6

N2 - The structure of the title compound, [Cd(dca)2(bpno) 2(H2O)2], contains a Cd atom coordinated by bpno (4,4′-bipyridine N,N′-dioxide, C10H 8N2O2), dca [dca is dicyanamide, N(CN) 2-] and two water molecules. The central CdII ion is located at an inversion center, coordinated by two N atoms from dca, two O atoms from bpno and two O atoms from water molecules, in an approximately octahedral geometry. This discrete structure is further extended to form a two-dimensional layer structure involving weak hydrogen bonds. The compound is isostructural with its cobalt analog [Aneta, Zdirad, Augustin, Jiri & Marius (2003). Polyhedron, 22, 789-794].

AB - The structure of the title compound, [Cd(dca)2(bpno) 2(H2O)2], contains a Cd atom coordinated by bpno (4,4′-bipyridine N,N′-dioxide, C10H 8N2O2), dca [dca is dicyanamide, N(CN) 2-] and two water molecules. The central CdII ion is located at an inversion center, coordinated by two N atoms from dca, two O atoms from bpno and two O atoms from water molecules, in an approximately octahedral geometry. This discrete structure is further extended to form a two-dimensional layer structure involving weak hydrogen bonds. The compound is isostructural with its cobalt analog [Aneta, Zdirad, Augustin, Jiri & Marius (2003). Polyhedron, 22, 789-794].

UR - https://www.scopus.com/pages/publications/18444384242

U2 - 10.1107/S1600536804010281

DO - 10.1107/S1600536804010281

M3 - Article

AN - SCOPUS:18444384242

SN - 1600-5368

VL - 60

SP - m713-m714

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Diaquabis(4,4′-bipyridine N,N′-dioxide-kO)-bis(dicyanamido) cadmium(II)

Abstract

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