Designed synthesis of POM-organic frameworks from {Ni6PW 9} building blocks under hydrothermal conditions

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1002/anie.200705709

Designed synthesis of POM-organic frameworks from {Ni₆PW ₉} building blocks under hydrothermal conditions

Shou Tian Zheng^*, Jie Zhang, Guo Yu Yang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

467 Citations (Scopus)

Abstract

Directed combination of {Ni₆PW₉} building blocks with various rigid carboxylate linkers under hydrothermal conditions yields a series of unprecedented polyoxometalate-organic frameworks (POMOFs) with remarkable structural diversity including 1D, 2D, and 3D structures based on monomers, dimers, or infinite helical chains (see picture for 3D structure: WO ₆: red; NiO₆: green; PO₄: yellow; 1,2,4-benzenetricarboxylate: gold). (Figure Presented).

Original language	English
Pages (from-to)	3909-3913
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	21
DOIs	https://doi.org/10.1002/anie.200705709
Publication status	Published - 13 May 2008
Externally published	Yes

Keywords

Carboxylate ligands
Hydrothermal synthesis
Organic-inorganic hybrid composites
Polyoxometalates
Porous materials

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10.1002/anie.200705709

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title = "Designed synthesis of POM-organic frameworks from \{Ni6PW 9\} building blocks under hydrothermal conditions",

abstract = "Directed combination of \{Ni6PW9\} building blocks with various rigid carboxylate linkers under hydrothermal conditions yields a series of unprecedented polyoxometalate-organic frameworks (POMOFs) with remarkable structural diversity including 1D, 2D, and 3D structures based on monomers, dimers, or infinite helical chains (see picture for 3D structure: WO 6: red; NiO6: green; PO4: yellow; 1,2,4-benzenetricarboxylate: gold). (Figure Presented).",

keywords = "Carboxylate ligands, Hydrothermal synthesis, Organic-inorganic hybrid composites, Polyoxometalates, Porous materials",

author = "Zheng, \{Shou Tian\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2008",

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day = "13",

doi = "10.1002/anie.200705709",

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AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2008/5/13

Y1 - 2008/5/13

N2 - Directed combination of {Ni6PW9} building blocks with various rigid carboxylate linkers under hydrothermal conditions yields a series of unprecedented polyoxometalate-organic frameworks (POMOFs) with remarkable structural diversity including 1D, 2D, and 3D structures based on monomers, dimers, or infinite helical chains (see picture for 3D structure: WO 6: red; NiO6: green; PO4: yellow; 1,2,4-benzenetricarboxylate: gold). (Figure Presented).

AB - Directed combination of {Ni6PW9} building blocks with various rigid carboxylate linkers under hydrothermal conditions yields a series of unprecedented polyoxometalate-organic frameworks (POMOFs) with remarkable structural diversity including 1D, 2D, and 3D structures based on monomers, dimers, or infinite helical chains (see picture for 3D structure: WO 6: red; NiO6: green; PO4: yellow; 1,2,4-benzenetricarboxylate: gold). (Figure Presented).

KW - Carboxylate ligands

KW - Hydrothermal synthesis

KW - Organic-inorganic hybrid composites

KW - Polyoxometalates

KW - Porous materials

UR - https://www.scopus.com/pages/publications/52949116469

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DO - 10.1002/anie.200705709

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21

ER -

Designed synthesis of POM-organic frameworks from {Ni₆PW ₉} building blocks under hydrothermal conditions

Abstract

Keywords

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