Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Xin Xiong Li^*
, Lin Jie Zhang
, Cai Yan Cui
, Rui Hu Wang
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Two unprecedented examples of cluster organic frameworks (TBA)₃Cu[V₆O₁₃(L)₂]₂·4DEF (2) (TBA)Ag[V₆O₁₃(L)₂] solvent (3) (TBA = tetrabutylammonium, H₃L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

Original language	English
Pages (from-to)	10323-10330
Number of pages	8
Journal	Inorganic Chemistry
Volume	57
Issue number	16
DOIs	https://doi.org/10.1021/acs.inorgchem.8b01528
Publication status	Published - 20 Aug 2018

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TY - JOUR

T1 - Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

AU - Li, Xin Xiong

AU - Zhang, Lin Jie

AU - Cui, Cai Yan

AU - Wang, Rui Hu

AU - Yang, Guo Yu

PY - 2018/8/20

Y1 - 2018/8/20

N2 - Two unprecedented examples of cluster organic frameworks (TBA)3Cu[V6O13(L)2]2·4DEF (2) (TBA)Ag[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

AB - Two unprecedented examples of cluster organic frameworks (TBA)3Cu[V6O13(L)2]2·4DEF (2) (TBA)Ag[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

UR - https://www.scopus.com/pages/publications/85051857454

U2 - 10.1021/acs.inorgchem.8b01528

DO - 10.1021/acs.inorgchem.8b01528

M3 - Article

C2 - 30094991

AN - SCOPUS:85051857454

SN - 0020-1669

VL - 57

SP - 10323

EP - 10330

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Abstract

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