Designed assembly of heterometallic cluster organic frameworks based on anderson-type polyoxometalate clusters

Xin Xiong Li; Yang Xin Wang; Rui Hu Wang; Cai Yan Cui; Chong Bin Tian; Guo Yu Yang

doi:10.1002/anie.201602087

Designed assembly of heterometallic cluster organic frameworks based on anderson-type polyoxometalate clusters

Xin Xiong Li, Yang Xin Wang, Rui Hu Wang^*, Cai Yan Cui, Chong Bin Tian, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

175 Citations (Scopus)

Abstract

A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson-type polyoxometalate (POM) clusters and transition-metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three-fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson-type POM clusters and cuprous iodide clusters into one cluster organic framework. All linked up: Two unprecedented heterometallic cluster organic frameworks were constructed through directly linking Anderson-type polyoxometalate (POM) clusters with different cuprous iodide clusters by using a rigid bifunctional tris(alkoxo) ligand under solvothermal conditions.

Original language	English
Pages (from-to)	6462-6466
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	22
DOIs	https://doi.org/10.1002/anie.201602087
Publication status	Published - 23 May 2016

Keywords

cluster organic frameworks
copper
heterometallic structures
luminescence
polyoxometalates

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10.1002/anie.201602087

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title = "Designed assembly of heterometallic cluster organic frameworks based on anderson-type polyoxometalate clusters",

abstract = "A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson-type polyoxometalate (POM) clusters and transition-metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three-fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson-type POM clusters and cuprous iodide clusters into one cluster organic framework. All linked up: Two unprecedented heterometallic cluster organic frameworks were constructed through directly linking Anderson-type polyoxometalate (POM) clusters with different cuprous iodide clusters by using a rigid bifunctional tris(alkoxo) ligand under solvothermal conditions.",

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author = "Li, {Xin Xiong} and Wang, {Yang Xin} and Wang, {Rui Hu} and Cui, {Cai Yan} and Tian, {Chong Bin} and Yang, {Guo Yu}",

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doi = "10.1002/anie.201602087",

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AU - Li, Xin Xiong

AU - Wang, Yang Xin

AU - Wang, Rui Hu

AU - Cui, Cai Yan

AU - Tian, Chong Bin

AU - Yang, Guo Yu

PY - 2016/5/23

Y1 - 2016/5/23

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AB - A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson-type polyoxometalate (POM) clusters and transition-metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three-fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson-type POM clusters and cuprous iodide clusters into one cluster organic framework. All linked up: Two unprecedented heterometallic cluster organic frameworks were constructed through directly linking Anderson-type polyoxometalate (POM) clusters with different cuprous iodide clusters by using a rigid bifunctional tris(alkoxo) ligand under solvothermal conditions.

KW - cluster organic frameworks

KW - copper

KW - heterometallic structures

KW - luminescence

KW - polyoxometalates

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Designed assembly of heterometallic cluster organic frameworks based on anderson-type polyoxometalate clusters

Abstract

Keywords

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