Defect locating: One-step to monodispersed CoFe₂O₄/rGO nanoparticles for oxygen reduction and oxygen evolution

In this work, monodispersed CoFe₂O₄/reduced graphene oxide (rGO) nanoparticles have been successfully synthetized in one step from Co(Ⅱ) acetylacetonate, Fe(Ⅲ) acetylacetonate, benzylamine and graphene oxide (GO). A facile solvent method was designed to skillfully integrate the crystal growth process of CoFe₂O₄, the reduction process of GO and their compound process. In synthesis process, large numbers of defects on GO thin layers were smartly used to disperse CoFe₂O₄ nanoparticles. The micromorphology and the distribution of as-prepared samples were identified via X-ray diffraction (XRD), transmission electron microscope (TEM) and element mapping spectra. Results showed that the monodispersed CoFe₂O₄ nanoparticles were uniformly coupled with rGO thin layers. Good performance for both oxygen reduction and oxygen evolution of as-prepared CoFe₂O₄/rGO (0.92 V onset potential for oxygen reduction and 1.59 V overpotential at 10 mA cm⁻² for oxygen evolution, vs. RHE) were found during a series of electrochemical tests, which make it a promising bi-functional catalyst in the field of fuel cells and metal-air batteries.