Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

You Ming Zhang; Jiang Yang Shao; Chang Jiang Yao; Yu Wu Zhong

doi:10.1039/c2dt31015e

Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

You Ming Zhang, Jiang Yang Shao, Chang Jiang Yao, Yu Wu Zhong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru ^II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

Original language	English
Pages (from-to)	9280-9282
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	31
DOIs	https://doi.org/10.1039/c2dt31015e
Publication status	Published - 21 Aug 2012
Externally published	Yes

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abstract = "The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.",

author = "Zhang, \{You Ming\} and Shao, \{Jiang Yang\} and Yao, \{Chang Jiang\} and Zhong, \{Yu Wu\}",

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AU - Zhang, You Ming

AU - Shao, Jiang Yang

AU - Yao, Chang Jiang

AU - Zhong, Yu Wu

PY - 2012/8/21

Y1 - 2012/8/21

N2 - The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

AB - The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

UR - https://www.scopus.com/pages/publications/84864227819

U2 - 10.1039/c2dt31015e

DO - 10.1039/c2dt31015e

M3 - Article

AN - SCOPUS:84864227819

SN - 1477-9226

VL - 41

SP - 9280

EP - 9282

JO - Dalton Transactions

JF - Dalton Transactions

IS - 31

ER -

Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

Abstract

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