Cyanotetrazolylborohydride (CTB) anion-based ionic liquids with low viscosity and high energy capacity as ultrafast-igniting hypergolic fuels

Xingye Li; Hongyu Huo; Haibo Li; Fude Nie; Hongquan Yin; Fu Xue Chen

doi:10.1039/c7cc03766j

Cyanotetrazolylborohydride (CTB) anion-based ionic liquids with low viscosity and high energy capacity as ultrafast-igniting hypergolic fuels

Xingye Li
, Hongyu Huo
, Haibo Li
, Fude Nie
, Hongquan Yin
, Fu Xue Chen^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

A series of hypergolic cyanotetrazolylborohydride (CTB) anion-based ionic liquids have been synthesized by a straightforward N-hydroboration of tetrazole followed by a salt metathesis reaction, which exhibited remarkably low viscosity (<20 mPa s), high density (often >1.1 g cm^-3), and ultra-short ignition delay time (as short as 1.4 ms) upon contact with white fuming nitric acid (WFNA).

Original language	English
Pages (from-to)	8300-8303
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	59
DOIs	https://doi.org/10.1039/c7cc03766j
Publication status	Published - 2017

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abstract = "A series of hypergolic cyanotetrazolylborohydride (CTB) anion-based ionic liquids have been synthesized by a straightforward N-hydroboration of tetrazole followed by a salt metathesis reaction, which exhibited remarkably low viscosity (<20 mPa s), high density (often >1.1 g cm-3), and ultra-short ignition delay time (as short as 1.4 ms) upon contact with white fuming nitric acid (WFNA).",

author = "Xingye Li and Hongyu Huo and Haibo Li and Fude Nie and Hongquan Yin and Chen, \{Fu Xue\}",

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AU - Li, Xingye

AU - Huo, Hongyu

AU - Li, Haibo

AU - Nie, Fude

AU - Yin, Hongquan

AU - Chen, Fu Xue

PY - 2017

Y1 - 2017

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AB - A series of hypergolic cyanotetrazolylborohydride (CTB) anion-based ionic liquids have been synthesized by a straightforward N-hydroboration of tetrazole followed by a salt metathesis reaction, which exhibited remarkably low viscosity (<20 mPa s), high density (often >1.1 g cm-3), and ultra-short ignition delay time (as short as 1.4 ms) upon contact with white fuming nitric acid (WFNA).

UR - https://www.scopus.com/pages/publications/85025159161

U2 - 10.1039/c7cc03766j

DO - 10.1039/c7cc03766j

M3 - Article

C2 - 28685780

AN - SCOPUS:85025159161

SN - 1359-7345

VL - 53

SP - 8300

EP - 8303

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Cyanotetrazolylborohydride (CTB) anion-based ionic liquids with low viscosity and high energy capacity as ultrafast-igniting hypergolic fuels

Abstract

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