[Cu(enMe)2]4[H5VIV 18O42(Cl)]·8H2O: Synthesis and crystal structure of microporous material constructed from metal-oxo cluster building blocks and metal complex fragments

Xiao Bing Cui; Shou Tian Zheng; Lan Ding; Hong Ding; Guo Yu Yang

[Cu(enMe)₂]₄[H₅V^IV ₁₈O₄₂(Cl)]·8H₂O: Synthesis and crystal structure of microporous material constructed from metal-oxo cluster building blocks and metal complex fragments

Xiao Bing Cui^*
, Shou Tian Zheng
, Lan Ding
, Hong Ding
, Guo Yu Yang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
Jilin University
Nanjing University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new porous crystal of [Cu(enMe)₂]₄ [H ₅V^IV₁₈O₄₂(Cl)]·8H ₂O constructed from metal-oxo cluster building blocks was hydrothermally synthesized and characterized by elemental analysis, IR, EPR and single-crystal X-ray diffraction. The compound crystallizes in tetragonal system, space group P4/nnc with a = 15.0034(3), c = 18.8149(3) Å, V = 4235.27(14) Å³, Z = 2, D_c = 2.055 g/cm³, M_r = 2620.74, μ = 2.988 mm^-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)_max = 0.969 × 10³ and (Δρ)_min = -0.454 × 10³ e/Å³. The structure is a three-dimensional framework linked alternatively by [H₅V^IV₁₈O ₄₂(Cl)]^8- polyoxoanions and [Cu(enMe)₂] complex cations.

Original language	English
Pages (from-to)	491-494
Number of pages	4
Journal	Jiegou Huaxue
Volume	22
Issue number	4
Publication status	Published - 2003
Externally published	Yes

Keywords

Copper
Crystal structure
Hydrothermal synthesis
Microporous material
Polyoxometalate
Vanadium

Cite this

@article{7f10bd7959fa4e4a9dbcf3027afa14a1,

title = "[Cu(enMe)2]4[H5VIV 18O42(Cl)]·8H2O: Synthesis and crystal structure of microporous material constructed from metal-oxo cluster building blocks and metal complex fragments",

abstract = "A new porous crystal of [Cu(enMe)2]4 [H 5VIV18O42(Cl)]·8H 2O constructed from metal-oxo cluster building blocks was hydrothermally synthesized and characterized by elemental analysis, IR, EPR and single-crystal X-ray diffraction. The compound crystallizes in tetragonal system, space group P4/nnc with a = 15.0034(3), c = 18.8149(3) {\AA}, V = 4235.27(14) {\AA}3, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, μ = 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)max = 0.969 {\texttimes} 103 and (Δρ)min = -0.454 {\texttimes} 103 e/{\AA}3. The structure is a three-dimensional framework linked alternatively by [H5VIV18O 42(Cl)]8- polyoxoanions and [Cu(enMe)2] complex cations.",

keywords = "Copper, Crystal structure, Hydrothermal synthesis, Microporous material, Polyoxometalate, Vanadium",

author = "Cui, \{Xiao Bing\} and Zheng, \{Shou Tian\} and Lan Ding and Hong Ding and Yang, \{Guo Yu\}",

year = "2003",

language = "English",

volume = "22",

pages = "491--494",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "4",

}

TY - JOUR

T1 - [Cu(enMe)2]4[H5VIV 18O42(Cl)]·8H2O

T2 - Synthesis and crystal structure of microporous material constructed from metal-oxo cluster building blocks and metal complex fragments

AU - Cui, Xiao Bing

AU - Zheng, Shou Tian

AU - Ding, Lan

AU - Ding, Hong

AU - Yang, Guo Yu

PY - 2003

Y1 - 2003

N2 - A new porous crystal of [Cu(enMe)2]4 [H 5VIV18O42(Cl)]·8H 2O constructed from metal-oxo cluster building blocks was hydrothermally synthesized and characterized by elemental analysis, IR, EPR and single-crystal X-ray diffraction. The compound crystallizes in tetragonal system, space group P4/nnc with a = 15.0034(3), c = 18.8149(3) Å, V = 4235.27(14) Å3, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, μ = 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)max = 0.969 × 103 and (Δρ)min = -0.454 × 103 e/Å3. The structure is a three-dimensional framework linked alternatively by [H5VIV18O 42(Cl)]8- polyoxoanions and [Cu(enMe)2] complex cations.

AB - A new porous crystal of [Cu(enMe)2]4 [H 5VIV18O42(Cl)]·8H 2O constructed from metal-oxo cluster building blocks was hydrothermally synthesized and characterized by elemental analysis, IR, EPR and single-crystal X-ray diffraction. The compound crystallizes in tetragonal system, space group P4/nnc with a = 15.0034(3), c = 18.8149(3) Å, V = 4235.27(14) Å3, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, μ = 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)max = 0.969 × 103 and (Δρ)min = -0.454 × 103 e/Å3. The structure is a three-dimensional framework linked alternatively by [H5VIV18O 42(Cl)]8- polyoxoanions and [Cu(enMe)2] complex cations.

KW - Copper

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Microporous material

KW - Polyoxometalate

KW - Vanadium

UR - https://www.scopus.com/pages/publications/0041382534

M3 - Article

AN - SCOPUS:0041382534

SN - 0254-5861

VL - 22

SP - 491

EP - 494

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 4

ER -

[Cu(enMe)₂]₄[H₅V^IV ₁₈O₄₂(Cl)]·8H₂O: Synthesis and crystal structure of microporous material constructed from metal-oxo cluster building blocks and metal complex fragments

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Keywords

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