CsBxGe6-xO12 (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

Rui Pan; Jian Wen Cheng; Bai Feng Yang; Guo Yu Yang

doi:10.1021/acs.inorgchem.6b03002

CsB_xGe_6-xO₁₂ (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

Rui Pan
, Jian Wen Cheng^*
, Bai Feng Yang
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsB_xGe_6-xO₁₂ (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.

Original language	English
Pages (from-to)	2371-2374
Number of pages	4
Journal	Inorganic Chemistry
Volume	56
Issue number	5
DOIs	https://doi.org/10.1021/acs.inorgchem.6b03002
Publication status	Published - 6 Mar 2017

Access to Document

10.1021/acs.inorgchem.6b03002

Cite this

@article{1cc9d6c512a041e2948872832c3a03d8,

title = "CsBxGe6-xO12 (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution",

abstract = "The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBxGe6-xO12 (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.",

author = "Rui Pan and Cheng, \{Jian Wen\} and Yang, \{Bai Feng\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = mar,

day = "6",

doi = "10.1021/acs.inorgchem.6b03002",

language = "English",

volume = "56",

pages = "2371--2374",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - CsBxGe6-xO12 (x = 1)

T2 - A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

AU - Pan, Rui

AU - Cheng, Jian Wen

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2017/3/6

Y1 - 2017/3/6

N2 - The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBxGe6-xO12 (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.

AB - The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBxGe6-xO12 (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.

UR - https://www.scopus.com/pages/publications/85014518653

U2 - 10.1021/acs.inorgchem.6b03002

DO - 10.1021/acs.inorgchem.6b03002

M3 - Article

C2 - 28218532

AN - SCOPUS:85014518653

SN - 0020-1669

VL - 56

SP - 2371

EP - 2374

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -

CsB_xGe_6-xO₁₂ (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

Abstract

Access to Document

Other files and links

Fingerprint

Cite this