CsBxGe6-xO12 (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

Rui Pan; Jian Wen Cheng; Bai Feng Yang; Guo Yu Yang

doi:10.1021/acs.inorgchem.6b03002

CsB_xGe_6-xO₁₂ (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

Rui Pan, Jian Wen Cheng^*, Bai Feng Yang, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsB_xGe_6-xO₁₂ (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.

Original language	English
Pages (from-to)	2371-2374
Number of pages	4
Journal	Inorganic Chemistry
Volume	56
Issue number	5
DOIs	https://doi.org/10.1021/acs.inorgchem.6b03002
Publication status	Published - 6 Mar 2017

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10.1021/acs.inorgchem.6b03002

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title = "CsBxGe6-xO12 (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution",

abstract = "The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBxGe6-xO12 (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.",

author = "Rui Pan and Cheng, {Jian Wen} and Yang, {Bai Feng} and Yang, {Guo Yu}",

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T2 - A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

AU - Pan, Rui

AU - Cheng, Jian Wen

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2017/3/6

Y1 - 2017/3/6

N2 - The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBxGe6-xO12 (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.

AB - The partial replacement of Ge atoms in tetrahedral positions by a small number of B atoms leads to a new microporous borogermanate, CsBxGe6-xO12 (x = 1), under solvothermal conditions. Its framework shows the highest atomic ratios of Ge/B in reported borogermanates and leads to a new type of zeolite sodalite-type net.

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DO - 10.1021/acs.inorgchem.6b03002

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CsB_xGe_6-xO₁₂ (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

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