Crystallographic evidence and spin activation for the Russian-doll-type metallofullerene Sc4C2@C80

Mingzhe Nie; Haibing Meng; Chong Zhao; Yuxi Lu; Jie Zhang; Lai Feng; Chunru Wang; Taishan Wang

doi:10.1039/d0cc04496b

Crystallographic evidence and spin activation for the Russian-doll-type metallofullerene Sc₄C₂@C₈₀

Mingzhe Nie
, Haibing Meng
, Chong Zhao
, Yuxi Lu
, Jie Zhang
, Lai Feng^*
, Chunru Wang
, Taishan Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We report unambiguous crystallographic evidence for the Russian-doll-type metallofullerene Sc₄C₂@I_h-C₈₀⁴⁵Sc NMR further demonstrates the tetrahedron arrangement of the Sc₄C₂cluster. Moreover, the electrochemical test reveals the stable oxidation state of Sc₄C₂@C₈₀. Hence, the Sc₄C₂@C₈₀cation radical was studied by electron spin resonance spectroscopy.

Original language	English
Pages (from-to)	10879-10882
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	74
DOIs	https://doi.org/10.1039/d0cc04496b
Publication status	Published - 21 Sept 2020
Externally published	Yes

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title = "Crystallographic evidence and spin activation for the Russian-doll-type metallofullerene Sc4C2@C80",

abstract = "We report unambiguous crystallographic evidence for the Russian-doll-type metallofullerene Sc4C2@Ih-C8045Sc NMR further demonstrates the tetrahedron arrangement of the Sc4C2cluster. Moreover, the electrochemical test reveals the stable oxidation state of Sc4C2@C80. Hence, the Sc4C2@C80cation radical was studied by electron spin resonance spectroscopy.",

author = "Mingzhe Nie and Haibing Meng and Chong Zhao and Yuxi Lu and Jie Zhang and Lai Feng and Chunru Wang and Taishan Wang",

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T1 - Crystallographic evidence and spin activation for the Russian-doll-type metallofullerene Sc4C2@C80

AU - Nie, Mingzhe

AU - Meng, Haibing

AU - Zhao, Chong

AU - Lu, Yuxi

AU - Zhang, Jie

AU - Feng, Lai

AU - Wang, Chunru

AU - Wang, Taishan

PY - 2020/9/21

Y1 - 2020/9/21

N2 - We report unambiguous crystallographic evidence for the Russian-doll-type metallofullerene Sc4C2@Ih-C8045Sc NMR further demonstrates the tetrahedron arrangement of the Sc4C2cluster. Moreover, the electrochemical test reveals the stable oxidation state of Sc4C2@C80. Hence, the Sc4C2@C80cation radical was studied by electron spin resonance spectroscopy.

AB - We report unambiguous crystallographic evidence for the Russian-doll-type metallofullerene Sc4C2@Ih-C8045Sc NMR further demonstrates the tetrahedron arrangement of the Sc4C2cluster. Moreover, the electrochemical test reveals the stable oxidation state of Sc4C2@C80. Hence, the Sc4C2@C80cation radical was studied by electron spin resonance spectroscopy.

UR - https://www.scopus.com/pages/publications/85091191947

U2 - 10.1039/d0cc04496b

DO - 10.1039/d0cc04496b

M3 - Article

C2 - 32804991

AN - SCOPUS:85091191947

SN - 1359-7345

VL - 56

SP - 10879

EP - 10882

JO - Chemical Communications

JF - Chemical Communications

IS - 74

ER -

Crystallographic evidence and spin activation for the Russian-doll-type metallofullerene Sc₄C₂@C₈₀

Abstract

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