Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes

Guanming Liao; Jia Zhang; Xiaoyan Zheng; Xiaodi Jia; Jialiang Xu; Fenggui Zhao; Nan Wang; Kanglei Liu; Bangkuan Chen; Xiaodong Yin

doi:10.1039/d1cc03311e

Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes

Guanming Liao
, Jia Zhang
, Xiaoyan Zheng^*
, Xiaodi Jia
, Jialiang Xu
, Fenggui Zhao
, Nan Wang
, Kanglei Liu
, Bangkuan Chen
, Xiaodong Yin

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A highly electron-deficient dicyanomethylene-bridged triarylborane,^FMesB-TCN, was reported with a low-lying LUMO and crystallization-induced emission enhancement in its block-shape crystal. DFT calculations revealed lower re-organization energy of the block crystal than that of the weakly emissive acicular crystal. This work explored a novel boron-containing skeleton with interesting optical properties.

Original language	English
Pages (from-to)	7926-7929
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	64
DOIs	https://doi.org/10.1039/d1cc03311e
Publication status	Published - 18 Aug 2021

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title = "Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes",

abstract = "A highly electron-deficient dicyanomethylene-bridged triarylborane,FMesB-TCN, was reported with a low-lying LUMO and crystallization-induced emission enhancement in its block-shape crystal. DFT calculations revealed lower re-organization energy of the block crystal than that of the weakly emissive acicular crystal. This work explored a novel boron-containing skeleton with interesting optical properties.",

author = "Guanming Liao and Jia Zhang and Xiaoyan Zheng and Xiaodi Jia and Jialiang Xu and Fenggui Zhao and Nan Wang and Kanglei Liu and Bangkuan Chen and Xiaodong Yin",

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year = "2021",

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TY - JOUR

T1 - Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes

AU - Liao, Guanming

AU - Zhang, Jia

AU - Zheng, Xiaoyan

AU - Jia, Xiaodi

AU - Xu, Jialiang

AU - Zhao, Fenggui

AU - Wang, Nan

AU - Liu, Kanglei

AU - Chen, Bangkuan

AU - Yin, Xiaodong

PY - 2021/8/18

Y1 - 2021/8/18

N2 - A highly electron-deficient dicyanomethylene-bridged triarylborane,FMesB-TCN, was reported with a low-lying LUMO and crystallization-induced emission enhancement in its block-shape crystal. DFT calculations revealed lower re-organization energy of the block crystal than that of the weakly emissive acicular crystal. This work explored a novel boron-containing skeleton with interesting optical properties.

AB - A highly electron-deficient dicyanomethylene-bridged triarylborane,FMesB-TCN, was reported with a low-lying LUMO and crystallization-induced emission enhancement in its block-shape crystal. DFT calculations revealed lower re-organization energy of the block crystal than that of the weakly emissive acicular crystal. This work explored a novel boron-containing skeleton with interesting optical properties.

UR - https://www.scopus.com/pages/publications/85112467925

U2 - 10.1039/d1cc03311e

DO - 10.1039/d1cc03311e

M3 - Article

C2 - 34286739

AN - SCOPUS:85112467925

SN - 1359-7345

VL - 57

SP - 7926

EP - 7929

JO - Chemical Communications

JF - Chemical Communications

IS - 64

ER -

Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes

Abstract

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