Crystal transition of HNIW in nitrate acid

Shao Hua Jin; Bo Yang; Jin Quan Liu; Xiang Dong Lei; Shu Sen Chen

Crystal transition of HNIW in nitrate acid

Shao Hua Jin^*
, Bo Yang
, Jin Quan Liu
, Xiang Dong Lei
, Shu Sen Chen

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology
CASIC Beijing

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Solubility of hexanitrohexaazaisowurzitane (HNIW) and its changes with temperature in three kinds of different concentrations of nitric acid were measured. The process of crystal transition from α, γ-HNIW to ε-HNIW in nitrate acid was studied. ε-HNIW with different crystal quality were obtained by changing concentration of HNO₃, temperature of adding crystal seeds, stirring rate. ε-HNIW is obtained in 90% nitric acid when the temperature of adding crystal seeds is in the range of 34-40°C. Its yield and purity is over 98%, 99% respectively, and acid number is below 2‰ (as HNO₃).

Original language	English
Pages (from-to)	656-659
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	15
Issue number	6
Publication status	Published - Dec 2007

Keywords

Applied chemistry
Crystal transition
Distribution of granularity
Hexanitrohexaazaisowurzitane (HNIW)
Solubility

Cite this

@article{ce5543db30f44a7da146dd630303204c,

title = "Crystal transition of HNIW in nitrate acid",

abstract = "Solubility of hexanitrohexaazaisowurzitane (HNIW) and its changes with temperature in three kinds of different concentrations of nitric acid were measured. The process of crystal transition from α, γ-HNIW to ε-HNIW in nitrate acid was studied. ε-HNIW with different crystal quality were obtained by changing concentration of HNO3, temperature of adding crystal seeds, stirring rate. ε-HNIW is obtained in 90\% nitric acid when the temperature of adding crystal seeds is in the range of 34-40°C. Its yield and purity is over 98\%, 99\% respectively, and acid number is below 2‰ (as HNO3).",

keywords = "Applied chemistry, Crystal transition, Distribution of granularity, Hexanitrohexaazaisowurzitane (HNIW), Solubility",

author = "Jin, \{Shao Hua\} and Bo Yang and Liu, \{Jin Quan\} and Lei, \{Xiang Dong\} and Chen, \{Shu Sen\}",

year = "2007",

month = dec,

language = "English",

volume = "15",

pages = "656--659",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "6",

}

TY - JOUR

T1 - Crystal transition of HNIW in nitrate acid

AU - Jin, Shao Hua

AU - Yang, Bo

AU - Liu, Jin Quan

AU - Lei, Xiang Dong

AU - Chen, Shu Sen

PY - 2007/12

Y1 - 2007/12

N2 - Solubility of hexanitrohexaazaisowurzitane (HNIW) and its changes with temperature in three kinds of different concentrations of nitric acid were measured. The process of crystal transition from α, γ-HNIW to ε-HNIW in nitrate acid was studied. ε-HNIW with different crystal quality were obtained by changing concentration of HNO3, temperature of adding crystal seeds, stirring rate. ε-HNIW is obtained in 90% nitric acid when the temperature of adding crystal seeds is in the range of 34-40°C. Its yield and purity is over 98%, 99% respectively, and acid number is below 2‰ (as HNO3).

AB - Solubility of hexanitrohexaazaisowurzitane (HNIW) and its changes with temperature in three kinds of different concentrations of nitric acid were measured. The process of crystal transition from α, γ-HNIW to ε-HNIW in nitrate acid was studied. ε-HNIW with different crystal quality were obtained by changing concentration of HNO3, temperature of adding crystal seeds, stirring rate. ε-HNIW is obtained in 90% nitric acid when the temperature of adding crystal seeds is in the range of 34-40°C. Its yield and purity is over 98%, 99% respectively, and acid number is below 2‰ (as HNO3).

KW - Applied chemistry

KW - Crystal transition

KW - Distribution of granularity

KW - Hexanitrohexaazaisowurzitane (HNIW)

KW - Solubility

UR - https://www.scopus.com/pages/publications/38349054488

M3 - Article

AN - SCOPUS:38349054488

SN - 1006-9941

VL - 15

SP - 656

EP - 659

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

Crystal transition of HNIW in nitrate acid

Abstract

Keywords

Other files and links

Fingerprint

Cite this