Crystal structure of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine

Mou Sun; Jian Guo Zhang; Jin Ling Feng; Jin Ting Wu; Tong Lai Zhang; Yuan Jie Shu

doi:10.3969/j.issn.1006-9941.2012.06.032

Crystal structure of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine

Mou Sun
, Jian Guo Zhang^*
, Jin Ling Feng
, Jin Ting Wu
, Tong Lai Zhang
, Yuan Jie Shu

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology
China Academy of Engineering Physics

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

3, 6-Bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine (BT) was prepared by oxidation of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2-dihydro-1, 2, 4, 5-tetrazine (BDT) with NO₂. The single crystal was cultured in anhydrous alcohol using slow evaporation method, and was determined by X-ray diffraction analysis. The molecule belongs to monoclinic system, space group P₂(1)/c, with crystal parameters of a=1.096 nm, b=1.651 nm, c=0.714 nm, β=103.895(4)°, Z=4.

Original language	English
Pages (from-to)	812-813
Number of pages	2
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	20
Issue number	6
DOIs	https://doi.org/10.3969/j.issn.1006-9941.2012.06.032
Publication status	Published - Dec 2012

Keywords

3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine
Crystal structure
Physical chemistry
Synthesis

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10.3969/j.issn.1006-9941.2012.06.032

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@article{67c99db5bf9d4af29d8e7bafffa5d396,

title = "Crystal structure of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine",

abstract = "3, 6-Bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine (BT) was prepared by oxidation of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2-dihydro-1, 2, 4, 5-tetrazine (BDT) with NO2. The single crystal was cultured in anhydrous alcohol using slow evaporation method, and was determined by X-ray diffraction analysis. The molecule belongs to monoclinic system, space group P2(1)/c, with crystal parameters of a=1.096 nm, b=1.651 nm, c=0.714 nm, β=103.895(4)°, Z=4.",

keywords = "3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine, Crystal structure, Physical chemistry, Synthesis",

author = "Mou Sun and Zhang, \{Jian Guo\} and Feng, \{Jin Ling\} and Wu, \{Jin Ting\} and Zhang, \{Tong Lai\} and Shu, \{Yuan Jie\}",

year = "2012",

month = dec,

doi = "10.3969/j.issn.1006-9941.2012.06.032",

language = "English",

volume = "20",

pages = "812--813",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "6",

}

TY - JOUR

T1 - Crystal structure of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine

AU - Sun, Mou

AU - Zhang, Jian Guo

AU - Feng, Jin Ling

AU - Wu, Jin Ting

AU - Zhang, Tong Lai

AU - Shu, Yuan Jie

PY - 2012/12

Y1 - 2012/12

N2 - 3, 6-Bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine (BT) was prepared by oxidation of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2-dihydro-1, 2, 4, 5-tetrazine (BDT) with NO2. The single crystal was cultured in anhydrous alcohol using slow evaporation method, and was determined by X-ray diffraction analysis. The molecule belongs to monoclinic system, space group P2(1)/c, with crystal parameters of a=1.096 nm, b=1.651 nm, c=0.714 nm, β=103.895(4)°, Z=4.

AB - 3, 6-Bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine (BT) was prepared by oxidation of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2-dihydro-1, 2, 4, 5-tetrazine (BDT) with NO2. The single crystal was cultured in anhydrous alcohol using slow evaporation method, and was determined by X-ray diffraction analysis. The molecule belongs to monoclinic system, space group P2(1)/c, with crystal parameters of a=1.096 nm, b=1.651 nm, c=0.714 nm, β=103.895(4)°, Z=4.

KW - 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine

KW - Crystal structure

KW - Physical chemistry

KW - Synthesis

UR - https://www.scopus.com/pages/publications/84872767225

U2 - 10.3969/j.issn.1006-9941.2012.06.032

DO - 10.3969/j.issn.1006-9941.2012.06.032

M3 - Article

AN - SCOPUS:84872767225

SN - 1006-9941

VL - 20

SP - 812

EP - 813

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

Crystal structure of 3, 6-bis(3, 5-dimethylpyrazol-1-yl)-1, 2, 4, 5-tetrazine

Abstract

Keywords

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