Coupling CdS quantum dots with polyoxometalate-supported [Re(CO)3]+ catalysts for efficient photocatalytic CO2 reduction

Yongkang Liu; Yuanyuan Dong; Jiaxin Yang; Yeqin Feng; Mengyun Zhao; Yun Qin; Hongjin Lv

doi:10.1039/d5cc00726g

Coupling CdS quantum dots with polyoxometalate-supported [Re(CO)₃]⁺ catalysts for efficient photocatalytic CO₂ reduction

Yongkang Liu, Yuanyuan Dong^*, Jiaxin Yang, Yeqin Feng, Mengyun Zhao, Yun Qin, Hongjin Lv^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A coupled photocatalytic system has been constructed by integrating CdS quantum dots as a light-absorber and polyoxometalate-supported [Re(CO)₃]⁺ (POM-Re) catalysts, which exhibited efficient activity towards photoreduction of CO₂ to HCOOH. Mechanistic studies revealed that the favorable migration of photogenerated electrons endows Sb₂W₂₀Re₂ with efficient photocatalytic CO₂ reduction activity.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d5cc00726g
Publication status	Accepted/In press - 2025

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title = "Coupling CdS quantum dots with polyoxometalate-supported [Re(CO)3]+ catalysts for efficient photocatalytic CO2 reduction",

abstract = "A coupled photocatalytic system has been constructed by integrating CdS quantum dots as a light-absorber and polyoxometalate-supported [Re(CO)3]+ (POM-Re) catalysts, which exhibited efficient activity towards photoreduction of CO2 to HCOOH. Mechanistic studies revealed that the favorable migration of photogenerated electrons endows Sb2W20Re2 with efficient photocatalytic CO2 reduction activity.",

author = "Yongkang Liu and Yuanyuan Dong and Jiaxin Yang and Yeqin Feng and Mengyun Zhao and Yun Qin and Hongjin Lv",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

doi = "10.1039/d5cc00726g",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Coupling CdS quantum dots with polyoxometalate-supported [Re(CO)3]+ catalysts for efficient photocatalytic CO2 reduction

AU - Liu, Yongkang

AU - Dong, Yuanyuan

AU - Yang, Jiaxin

AU - Feng, Yeqin

AU - Zhao, Mengyun

AU - Qin, Yun

AU - Lv, Hongjin

PY - 2025

Y1 - 2025

N2 - A coupled photocatalytic system has been constructed by integrating CdS quantum dots as a light-absorber and polyoxometalate-supported [Re(CO)3]+ (POM-Re) catalysts, which exhibited efficient activity towards photoreduction of CO2 to HCOOH. Mechanistic studies revealed that the favorable migration of photogenerated electrons endows Sb2W20Re2 with efficient photocatalytic CO2 reduction activity.

AB - A coupled photocatalytic system has been constructed by integrating CdS quantum dots as a light-absorber and polyoxometalate-supported [Re(CO)3]+ (POM-Re) catalysts, which exhibited efficient activity towards photoreduction of CO2 to HCOOH. Mechanistic studies revealed that the favorable migration of photogenerated electrons endows Sb2W20Re2 with efficient photocatalytic CO2 reduction activity.

UR - http://www.scopus.com/inward/record.url?scp=105000689976&partnerID=8YFLogxK

U2 - 10.1039/d5cc00726g

DO - 10.1039/d5cc00726g

M3 - Article

AN - SCOPUS:105000689976

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Coupling CdS quantum dots with polyoxometalate-supported [Re(CO)₃]⁺ catalysts for efficient photocatalytic CO₂ reduction

Abstract

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