Coordination polymers: Structural transformation from two to three dimensions through ligand conformation change

Zhan Shi; Lirong Zhang; Shan Gao; Guoyu Yang; Jia Hua; Lu Gao; Shouhua Feng

doi:10.1021/ic991355q

Coordination polymers: Structural transformation from two to three dimensions through ligand conformation change

Zhan Shi, Lirong Zhang, Shan Gao, Guoyu Yang, Jia Hua, Lu Gao, Shouhua Feng^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

115 Citations (Scopus)

Abstract

Two coordination polymers of {[Mn(maleate)(μ-4,4'-bipy)]·0.5(H₂O)}∞ (1) and {[Mn(fumarate)(μ-4,4'-bipy)(H₂O)]·0.5(4,4'-bipy)}∞ (2) (bipy = bipyridine) were synthesized and structurally characterized. The 1-D [Mn(maleate)]₈ chains were formed by maleate molecules chelating Mn atoms, and these chains were connected with 4,4'-bipy to form a 2-D structure (structure 1). The 2-D [Mn(fumarate)(H₂O)]∞ layers were composed of the fumarate molecules coordinating different Mn ions, and these layers were linked with 4,4'-bipy to give a 3-D open framework (structure 2).

Original language	English
Pages (from-to)	1990-1993
Number of pages	4
Journal	Inorganic Chemistry
Volume	39
Issue number	9
DOIs	https://doi.org/10.1021/ic991355q
Publication status	Published - 1 May 2000
Externally published	Yes

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@article{bc495ace006f41ca8ad9aea6beb8d642,

title = "Coordination polymers: Structural transformation from two to three dimensions through ligand conformation change",

abstract = "Two coordination polymers of \{[Mn(maleate)(μ-4,4'-bipy)]·0.5(H2O)\}∞ (1) and \{[Mn(fumarate)(μ-4,4'-bipy)(H2O)]·0.5(4,4'-bipy)\}∞ (2) (bipy = bipyridine) were synthesized and structurally characterized. The 1-D [Mn(maleate)]8 chains were formed by maleate molecules chelating Mn atoms, and these chains were connected with 4,4'-bipy to form a 2-D structure (structure 1). The 2-D [Mn(fumarate)(H2O)]∞ layers were composed of the fumarate molecules coordinating different Mn ions, and these layers were linked with 4,4'-bipy to give a 3-D open framework (structure 2).",

author = "Zhan Shi and Lirong Zhang and Shan Gao and Guoyu Yang and Jia Hua and Lu Gao and Shouhua Feng",

year = "2000",

month = may,

day = "1",

doi = "10.1021/ic991355q",

language = "English",

volume = "39",

pages = "1990--1993",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Coordination polymers

T2 - Structural transformation from two to three dimensions through ligand conformation change

AU - Shi, Zhan

AU - Zhang, Lirong

AU - Gao, Shan

AU - Yang, Guoyu

AU - Hua, Jia

AU - Gao, Lu

AU - Feng, Shouhua

PY - 2000/5/1

Y1 - 2000/5/1

N2 - Two coordination polymers of {[Mn(maleate)(μ-4,4'-bipy)]·0.5(H2O)}∞ (1) and {[Mn(fumarate)(μ-4,4'-bipy)(H2O)]·0.5(4,4'-bipy)}∞ (2) (bipy = bipyridine) were synthesized and structurally characterized. The 1-D [Mn(maleate)]8 chains were formed by maleate molecules chelating Mn atoms, and these chains were connected with 4,4'-bipy to form a 2-D structure (structure 1). The 2-D [Mn(fumarate)(H2O)]∞ layers were composed of the fumarate molecules coordinating different Mn ions, and these layers were linked with 4,4'-bipy to give a 3-D open framework (structure 2).

AB - Two coordination polymers of {[Mn(maleate)(μ-4,4'-bipy)]·0.5(H2O)}∞ (1) and {[Mn(fumarate)(μ-4,4'-bipy)(H2O)]·0.5(4,4'-bipy)}∞ (2) (bipy = bipyridine) were synthesized and structurally characterized. The 1-D [Mn(maleate)]8 chains were formed by maleate molecules chelating Mn atoms, and these chains were connected with 4,4'-bipy to form a 2-D structure (structure 1). The 2-D [Mn(fumarate)(H2O)]∞ layers were composed of the fumarate molecules coordinating different Mn ions, and these layers were linked with 4,4'-bipy to give a 3-D open framework (structure 2).

UR - https://www.scopus.com/pages/publications/0034189928

U2 - 10.1021/ic991355q

DO - 10.1021/ic991355q

M3 - Article

C2 - 11428119

AN - SCOPUS:0034189928

SN - 0020-1669

VL - 39

SP - 1990

EP - 1993

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 9

ER -

Coordination polymers: Structural transformation from two to three dimensions through ligand conformation change

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