Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

Qingqing Liu; Yeqin Feng; Tianfu Liu; Mengyun Zhao; Yurui Li; Hongjin Lv; Guo Yu Yang

doi:10.1039/d5nr03313f

Controllable syntheses of two structurally new {AsW₉O₃₃}-mediated silver alkynyl clusters

Qingqing Liu, Yeqin Feng, Tianfu Liu^*, Mengyun Zhao, Yurui Li, Hongjin Lv^*, Guo Yu Yang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

In this work, two structurally new silver alkynyl clusters, [(AsW₉O₃₃)₂@Ag₄₈(NO₃)₆(^tBuC = C)₂₄(DMF)₆]·3CH₃CN (1) and [(AsW₉O₃₃)₂@Ag₅₆(NO₃)₄Cl₂(^tBuC C)₃₂]_n (2), were successfully synthesized using the trilacunary B-α-[AsW₉O₃₃]⁹⁻ as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

Original language	English
Pages (from-to)	21475-21480
Number of pages	6
Journal	Nanoscale
Volume	17
Issue number	37
DOIs	https://doi.org/10.1039/d5nr03313f
Publication status	Published - 25 Sept 2025
Externally published	Yes

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title = "Controllable syntheses of two structurally new \{AsW9O33\}-mediated silver alkynyl clusters",

abstract = "In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC = C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.",

author = "Qingqing Liu and Yeqin Feng and Tianfu Liu and Mengyun Zhao and Yurui Li and Hongjin Lv and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

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day = "25",

doi = "10.1039/d5nr03313f",

language = "English",

volume = "17",

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journal = "Nanoscale",

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TY - JOUR

T1 - Controllable syntheses of two structurally new {AsW9O33}-mediated silver alkynyl clusters

AU - Liu, Qingqing

AU - Feng, Yeqin

AU - Liu, Tianfu

AU - Zhao, Mengyun

AU - Li, Yurui

AU - Lv, Hongjin

AU - Yang, Guo Yu

PY - 2025/9/25

Y1 - 2025/9/25

N2 - In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC = C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

AB - In this work, two structurally new silver alkynyl clusters, [(AsW9O33)2@Ag48(NO3)6(tBuC = C)24(DMF)6]·3CH3CN (1) and [(AsW9O33)2@Ag56(NO3)4Cl2(tBuC C)32]n (2), were successfully synthesized using the trilacunary B-α-[AsW9O33]9− as an anionic template via a facile one-pot solvothermal approach. The molecular structures of clusters 1 and 2 can be controlled using different mixed reaction solvents. Compounds 1 and 2 also demonstrate efficient photothermal conversion properties and notable catalytic activities towards the detoxification of 4-nitrophenol.

UR - https://www.scopus.com/pages/publications/105017062534

U2 - 10.1039/d5nr03313f

DO - 10.1039/d5nr03313f

M3 - Article

C2 - 40905247

AN - SCOPUS:105017062534

SN - 2040-3364

VL - 17

SP - 21475

EP - 21480

JO - Nanoscale

JF - Nanoscale

IS - 37

ER -

Controllable syntheses of two structurally new {AsW₉O₃₃}-mediated silver alkynyl clusters

Abstract

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