Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

Jing Hui Zhou; Yu Xiao Chen; Zhi Kun Liu; Jie Sheng Hu; Lu Yao Wang; Yu Meng Zhao; Ling Tai Yue; Meng Yu; Jun Tao

doi:10.1002/ejic.202400132

Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

Jing Hui Zhou, Yu Xiao Chen, Zhi Kun Liu, Jie Sheng Hu, Lu Yao Wang, Yu Meng Zhao, Ling Tai Yue, Meng Yu^*, Jun Tao^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The incorporation of fluorescent properties into spin-crossover (SCO) materials, aiming at controlling fluorescence via spin-state transitions for applications in magneto-optical switching and information processing, represents an appealing research direction. In this study, we prepared two examples of one-dimensional cyclic chain-like Fe(II) coordination polymers, denoted as [Fe(DPPC)₂(NCS)₂]⋅CH₃OH⋅o-C₆H₄Cl₂ (1, DPPC=3,6-di-4-pyridinyl-9-[4-(4-pyridinyl)phenyl]-9H-carbazole) and [Fe(PDPC)₂(NCS)₂] (2, PDPC=3,6-di(pyridin-4-yl)-9-phenyl-9H-carbazole). Analyses through single-crystal X-ray studies and magnetic measurements validate the two-step SCO behavior of 1 within the temperature range of 50~200 K. Additionally, when combined with temperature-dependent fluorescence emission spectroscopy, the results demonstrate the coexistence of SCO and fluorescence in 1.

Original language	English
Article number	e202400132
Journal	European Journal of Inorganic Chemistry
Volume	27
Issue number	20
DOIs	https://doi.org/10.1002/ejic.202400132
Publication status	Published - 10 Jul 2024

Keywords

Carbazole
Fluorescence
Iron(II)
Spin Crossover
Synthesis

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10.1002/ejic.202400132

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title = "Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands",

abstract = "The incorporation of fluorescent properties into spin-crossover (SCO) materials, aiming at controlling fluorescence via spin-state transitions for applications in magneto-optical switching and information processing, represents an appealing research direction. In this study, we prepared two examples of one-dimensional cyclic chain-like Fe(II) coordination polymers, denoted as [Fe(DPPC)2(NCS)2]⋅CH3OH⋅o-C6H4Cl2 (1, DPPC=3,6-di-4-pyridinyl-9-[4-(4-pyridinyl)phenyl]-9H-carbazole) and [Fe(PDPC)2(NCS)2] (2, PDPC=3,6-di(pyridin-4-yl)-9-phenyl-9H-carbazole). Analyses through single-crystal X-ray studies and magnetic measurements validate the two-step SCO behavior of 1 within the temperature range of 50\textasciitilde{}200 K. Additionally, when combined with temperature-dependent fluorescence emission spectroscopy, the results demonstrate the coexistence of SCO and fluorescence in 1.",

keywords = "Carbazole, Fluorescence, Iron(II), Spin Crossover, Synthesis",

author = "Zhou, \{Jing Hui\} and Chen, \{Yu Xiao\} and Liu, \{Zhi Kun\} and Hu, \{Jie Sheng\} and Wang, \{Lu Yao\} and Zhao, \{Yu Meng\} and Yue, \{Ling Tai\} and Meng Yu and Jun Tao",

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year = "2024",

month = jul,

day = "10",

doi = "10.1002/ejic.202400132",

language = "English",

volume = "27",

journal = "European Journal of Inorganic Chemistry",

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TY - JOUR

T1 - Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

AU - Zhou, Jing Hui

AU - Chen, Yu Xiao

AU - Liu, Zhi Kun

AU - Hu, Jie Sheng

AU - Wang, Lu Yao

AU - Zhao, Yu Meng

AU - Yue, Ling Tai

AU - Yu, Meng

AU - Tao, Jun

PY - 2024/7/10

Y1 - 2024/7/10

N2 - The incorporation of fluorescent properties into spin-crossover (SCO) materials, aiming at controlling fluorescence via spin-state transitions for applications in magneto-optical switching and information processing, represents an appealing research direction. In this study, we prepared two examples of one-dimensional cyclic chain-like Fe(II) coordination polymers, denoted as [Fe(DPPC)2(NCS)2]⋅CH3OH⋅o-C6H4Cl2 (1, DPPC=3,6-di-4-pyridinyl-9-[4-(4-pyridinyl)phenyl]-9H-carbazole) and [Fe(PDPC)2(NCS)2] (2, PDPC=3,6-di(pyridin-4-yl)-9-phenyl-9H-carbazole). Analyses through single-crystal X-ray studies and magnetic measurements validate the two-step SCO behavior of 1 within the temperature range of 50~200 K. Additionally, when combined with temperature-dependent fluorescence emission spectroscopy, the results demonstrate the coexistence of SCO and fluorescence in 1.

AB - The incorporation of fluorescent properties into spin-crossover (SCO) materials, aiming at controlling fluorescence via spin-state transitions for applications in magneto-optical switching and information processing, represents an appealing research direction. In this study, we prepared two examples of one-dimensional cyclic chain-like Fe(II) coordination polymers, denoted as [Fe(DPPC)2(NCS)2]⋅CH3OH⋅o-C6H4Cl2 (1, DPPC=3,6-di-4-pyridinyl-9-[4-(4-pyridinyl)phenyl]-9H-carbazole) and [Fe(PDPC)2(NCS)2] (2, PDPC=3,6-di(pyridin-4-yl)-9-phenyl-9H-carbazole). Analyses through single-crystal X-ray studies and magnetic measurements validate the two-step SCO behavior of 1 within the temperature range of 50~200 K. Additionally, when combined with temperature-dependent fluorescence emission spectroscopy, the results demonstrate the coexistence of SCO and fluorescence in 1.

KW - Carbazole

KW - Fluorescence

KW - Iron(II)

KW - Spin Crossover

KW - Synthesis

UR - https://www.scopus.com/pages/publications/85195507370

U2 - 10.1002/ejic.202400132

DO - 10.1002/ejic.202400132

M3 - Article

AN - SCOPUS:85195507370

SN - 1434-1948

VL - 27

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 20

M1 - e202400132

ER -

Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

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Keywords

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