Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

Gang Zhao; Dheeraj Kumar; Ping Yin; Chunlin He; Gregory H. Imler; Damon A. Parrish; Jean'ne M. Shreeve

doi:10.1021/acs.orglett.8b04114

Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

Gang Zhao, Dheeraj Kumar, Ping Yin, Chunlin He, Gregory H. Imler, Damon A. Parrish, Jean'ne M. Shreeve^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm ³ confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.

Original language	English
Pages (from-to)	1073-1077
Number of pages	5
Journal	Organic Letters
Volume	21
Issue number	4
DOIs	https://doi.org/10.1021/acs.orglett.8b04114
Publication status	Published - 15 Feb 2019
Externally published	Yes

Access to Document

10.1021/acs.orglett.8b04114

Cite this

@article{6eef08a725da4ab3b3d52ebd27fc5265,

title = "Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups",

abstract = " An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm 3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.",

author = "Gang Zhao and Dheeraj Kumar and Ping Yin and Chunlin He and Imler, {Gregory H.} and Parrish, {Damon A.} and Shreeve, {Jean'ne M.}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = feb,

day = "15",

doi = "10.1021/acs.orglett.8b04114",

language = "English",

volume = "21",

pages = "1073--1077",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

AU - Zhao, Gang

AU - Kumar, Dheeraj

AU - Yin, Ping

AU - He, Chunlin

AU - Imler, Gregory H.

AU - Parrish, Damon A.

AU - Shreeve, Jean'ne M.

PY - 2019/2/15

Y1 - 2019/2/15

N2 - An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm 3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.

AB - An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm 3 confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.

UR - http://www.scopus.com/inward/record.url?scp=85061573117&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.8b04114

DO - 10.1021/acs.orglett.8b04114

M3 - Article

C2 - 30673255

AN - SCOPUS:85061573117

SN - 1523-7060

VL - 21

SP - 1073

EP - 1077

JO - Organic Letters

JF - Organic Letters

IS - 4

ER -

Construction of Polynitro Compounds as High-Performance Oxidizers via a Two-Step Nitration of Various Functional Groups

Abstract

Access to Document

Other files and links

Fingerprint

Cite this