Construction of Circular Polarized Luminescence Molecules for Intense Near Infrared OLEDs

Ning Liang; Jianxun Liu; Yufan Lin; Zeling Xie; Bin Bin Cui; Zhong Liang Gong; Qiang Gan; Yu Wu Zhong; Yansong Feng; Chang Jiang Yao

doi:10.1002/adom.202303155

Construction of Circular Polarized Luminescence Molecules for Intense Near Infrared OLEDs

Ning Liang, Jianxun Liu, Yufan Lin, Zeling Xie, Bin Bin Cui, Zhong Liang Gong, Qiang Gan, Yu Wu Zhong, Yansong Feng^*, Chang Jiang Yao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The exploration of organic near-infrared (NIR) luminescence, along with circularly polarized luminescence (CPL), is of vital importance due to its significance in medical and optoelectronic applications. Integrating a chiral unit into a D–A molecular structure in this research realized emission peaks at 744 nm, exhibiting a dissymmetric factor of −1.67 × 10⁻³. The introduced chiral TPA derivative not only imparts aggregation-induced emission properties and CPL capabilities but also induces a redshift in the emission spectrum. Consequently, the fabricated NIR organic light-emitting devices (OLEDs), achieve maximum electroluminescent peaks at 748 nm in nondoped devices with the external quantum efficiency of 13.7% in doped devices. This pioneering research provides inspiration for the design of NIR molecules possessing CPL properties in the future, particularly in promoting the application of intense NIR-OLEDs.

Original language	English
Article number	2303155
Journal	Advanced Optical Materials
Volume	12
Issue number	16
DOIs	https://doi.org/10.1002/adom.202303155
Publication status	Published - 6 Jun 2024

Keywords

chiral units
circularly polarized luminescence
near-infrared emission
organic light emitting diodes

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10.1002/adom.202303155

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@article{b151cca79e8d485988124f706e497469,

title = "Construction of Circular Polarized Luminescence Molecules for Intense Near Infrared OLEDs",

abstract = "The exploration of organic near-infrared (NIR) luminescence, along with circularly polarized luminescence (CPL), is of vital importance due to its significance in medical and optoelectronic applications. Integrating a chiral unit into a D–A molecular structure in this research realized emission peaks at 744 nm, exhibiting a dissymmetric factor of −1.67 × 10−3. The introduced chiral TPA derivative not only imparts aggregation-induced emission properties and CPL capabilities but also induces a redshift in the emission spectrum. Consequently, the fabricated NIR organic light-emitting devices (OLEDs), achieve maximum electroluminescent peaks at 748 nm in nondoped devices with the external quantum efficiency of 13.7% in doped devices. This pioneering research provides inspiration for the design of NIR molecules possessing CPL properties in the future, particularly in promoting the application of intense NIR-OLEDs.",

keywords = "chiral units, circularly polarized luminescence, near-infrared emission, organic light emitting diodes",

author = "Ning Liang and Jianxun Liu and Yufan Lin and Zeling Xie and Cui, {Bin Bin} and Gong, {Zhong Liang} and Qiang Gan and Zhong, {Yu Wu} and Yansong Feng and Yao, {Chang Jiang}",

note = "Publisher Copyright: {\textcopyright} 2024 Wiley-VCH GmbH.",

year = "2024",

month = jun,

day = "6",

doi = "10.1002/adom.202303155",

language = "English",

volume = "12",

journal = "Advanced Optical Materials",

issn = "2195-1071",

publisher = "John Wiley & Sons Inc.",

number = "16",

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TY - JOUR

T1 - Construction of Circular Polarized Luminescence Molecules for Intense Near Infrared OLEDs

AU - Liang, Ning

AU - Liu, Jianxun

AU - Lin, Yufan

AU - Xie, Zeling

AU - Cui, Bin Bin

AU - Gong, Zhong Liang

AU - Gan, Qiang

AU - Zhong, Yu Wu

AU - Feng, Yansong

AU - Yao, Chang Jiang

PY - 2024/6/6

Y1 - 2024/6/6

N2 - The exploration of organic near-infrared (NIR) luminescence, along with circularly polarized luminescence (CPL), is of vital importance due to its significance in medical and optoelectronic applications. Integrating a chiral unit into a D–A molecular structure in this research realized emission peaks at 744 nm, exhibiting a dissymmetric factor of −1.67 × 10−3. The introduced chiral TPA derivative not only imparts aggregation-induced emission properties and CPL capabilities but also induces a redshift in the emission spectrum. Consequently, the fabricated NIR organic light-emitting devices (OLEDs), achieve maximum electroluminescent peaks at 748 nm in nondoped devices with the external quantum efficiency of 13.7% in doped devices. This pioneering research provides inspiration for the design of NIR molecules possessing CPL properties in the future, particularly in promoting the application of intense NIR-OLEDs.

AB - The exploration of organic near-infrared (NIR) luminescence, along with circularly polarized luminescence (CPL), is of vital importance due to its significance in medical and optoelectronic applications. Integrating a chiral unit into a D–A molecular structure in this research realized emission peaks at 744 nm, exhibiting a dissymmetric factor of −1.67 × 10−3. The introduced chiral TPA derivative not only imparts aggregation-induced emission properties and CPL capabilities but also induces a redshift in the emission spectrum. Consequently, the fabricated NIR organic light-emitting devices (OLEDs), achieve maximum electroluminescent peaks at 748 nm in nondoped devices with the external quantum efficiency of 13.7% in doped devices. This pioneering research provides inspiration for the design of NIR molecules possessing CPL properties in the future, particularly in promoting the application of intense NIR-OLEDs.

KW - chiral units

KW - circularly polarized luminescence

KW - near-infrared emission

KW - organic light emitting diodes

UR - http://www.scopus.com/inward/record.url?scp=85187686643&partnerID=8YFLogxK

U2 - 10.1002/adom.202303155

DO - 10.1002/adom.202303155

M3 - Article

AN - SCOPUS:85187686643

SN - 2195-1071

VL - 12

JO - Advanced Optical Materials

JF - Advanced Optical Materials

IS - 16

M1 - 2303155

ER -

Construction of Circular Polarized Luminescence Molecules for Intense Near Infrared OLEDs

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Keywords

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