Concentrated fluoride-medium route to synthesis of one-dimensional fluoroaluminophosphate chain (C4H15N3)[ALPO4F2]

Yang Liu; Yi De Han; Yi Li; Xiao Wei Song; Ji Yang Li; Ji Hong Yu; Ru Ren Xu

Concentrated fluoride-medium route to synthesis of one-dimensional fluoroaluminophosphate chain (C₄H₁₅N₃)[ALPO₄F₂]

Yang Liu, Yi De Han, Yi Li, Xiao Wei Song, Ji Yang Li^*, Ji Hong Yu, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new one-dimensional(1D) fluoroaluminophosphate chain(C₄H₁₅N₃)[ALPO₄F₂](denoted AlPO-CJ28) was synthesized in the concentrated fluoride synthetic medium with a gel composition of 1.0Al(OPrⁱ)₃:1.0H₃PO₄: 5.4DETA:1.3HF:2.0H₂O(DETA=diethylenetriamine). The reagents were mixed directly without introducing additional water solvent. The 1D chain is constructed by alternating AlO₂F₂ and doubly bridging PO₄ tetrahedra to form the simplest serrate chain. AlPO-CJ28 can be transformed to another 1D aluminophosphate chain AlPO-CSC upon further crystallization at 230 °C.

Original language	English
Pages (from-to)	699-701
Number of pages	3
Journal	Chemical Research in Chinese Universities
Volume	26
Issue number	5
Publication status	Published - 2010
Externally published	Yes

Keywords

Chain structure
Concentrated fluoride-medium
Fluoroaluminophosphate
Phase transformation

Cite this

@article{246baa32b4e34d289de31985f1d91074,

title = "Concentrated fluoride-medium route to synthesis of one-dimensional fluoroaluminophosphate chain (C4H15N3)[ALPO4F2]",

abstract = "A new one-dimensional(1D) fluoroaluminophosphate chain(C4H15N3)[ALPO4F2](denoted AlPO-CJ28) was synthesized in the concentrated fluoride synthetic medium with a gel composition of 1.0Al(OPri)3:1.0H3PO4: 5.4DETA:1.3HF:2.0H2O(DETA=diethylenetriamine). The reagents were mixed directly without introducing additional water solvent. The 1D chain is constructed by alternating AlO2F2 and doubly bridging PO4 tetrahedra to form the simplest serrate chain. AlPO-CJ28 can be transformed to another 1D aluminophosphate chain AlPO-CSC upon further crystallization at 230 °C.",

keywords = "Chain structure, Concentrated fluoride-medium, Fluoroaluminophosphate, Phase transformation",

author = "Yang Liu and Han, {Yi De} and Yi Li and Song, {Xiao Wei} and Li, {Ji Yang} and Yu, {Ji Hong} and Xu, {Ru Ren}",

year = "2010",

language = "English",

volume = "26",

pages = "699--701",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

publisher = "Springer International Publishing AG",

number = "5",

}

TY - JOUR

T1 - Concentrated fluoride-medium route to synthesis of one-dimensional fluoroaluminophosphate chain (C4H15N3)[ALPO4F2]

AU - Liu, Yang

AU - Han, Yi De

AU - Li, Yi

AU - Song, Xiao Wei

AU - Li, Ji Yang

AU - Yu, Ji Hong

AU - Xu, Ru Ren

PY - 2010

Y1 - 2010

N2 - A new one-dimensional(1D) fluoroaluminophosphate chain(C4H15N3)[ALPO4F2](denoted AlPO-CJ28) was synthesized in the concentrated fluoride synthetic medium with a gel composition of 1.0Al(OPri)3:1.0H3PO4: 5.4DETA:1.3HF:2.0H2O(DETA=diethylenetriamine). The reagents were mixed directly without introducing additional water solvent. The 1D chain is constructed by alternating AlO2F2 and doubly bridging PO4 tetrahedra to form the simplest serrate chain. AlPO-CJ28 can be transformed to another 1D aluminophosphate chain AlPO-CSC upon further crystallization at 230 °C.

AB - A new one-dimensional(1D) fluoroaluminophosphate chain(C4H15N3)[ALPO4F2](denoted AlPO-CJ28) was synthesized in the concentrated fluoride synthetic medium with a gel composition of 1.0Al(OPri)3:1.0H3PO4: 5.4DETA:1.3HF:2.0H2O(DETA=diethylenetriamine). The reagents were mixed directly without introducing additional water solvent. The 1D chain is constructed by alternating AlO2F2 and doubly bridging PO4 tetrahedra to form the simplest serrate chain. AlPO-CJ28 can be transformed to another 1D aluminophosphate chain AlPO-CSC upon further crystallization at 230 °C.

KW - Chain structure

KW - Concentrated fluoride-medium

KW - Fluoroaluminophosphate

KW - Phase transformation

UR - http://www.scopus.com/inward/record.url?scp=80555156189&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:80555156189

SN - 1005-9040

VL - 26

SP - 699

EP - 701

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 5

ER -

Concentrated fluoride-medium route to synthesis of one-dimensional fluoroaluminophosphate chain (C₄H₁₅N₃)[ALPO₄F₂]

Abstract

Keywords

Other files and links

Fingerprint

Cite this