Abstract
The rational synthesis of open-framework materials with extra-large micropores is a challenging topic in the field of zeolites science. Employing computational methods, the charge-density matching, space matching, and non-bonding interactions of the host framework and guest template molecules have been studied for some known microporous materials with 14-, 16-, 18-, 20- and 24-ring extra-large micropores. The host-guest relationship in different synthetic systems has been summarized. This study provides a useful guidance for rational choice of templates for the synthesis of extra-large microporous materials with predetermined structures and compositions.
| Original language | English |
|---|---|
| Pages (from-to) | 406-412 |
| Number of pages | 7 |
| Journal | Microporous and Mesoporous Materials |
| Volume | 101 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 20 Apr 2007 |
| Externally published | Yes |
Keywords
- Charge-density matching
- Extra-large micropore
- Host-guest
- Non-bonding interaction
- Space matching