Composition-dependent catalytic activity of bimetallic nanocrystals: AgPd-catalyzed hydrodechlorination of 4-chlorophenol

Hongpan Rong; Shuangfei Cai; Zhiqiang Niu; Yadong Li

doi:10.1021/cs400282a

Composition-dependent catalytic activity of bimetallic nanocrystals: AgPd-catalyzed hydrodechlorination of 4-chlorophenol

Hongpan Rong, Shuangfei Cai, Zhiqiang Niu^*, Yadong Li

^*Corresponding author for this work

Tsinghua University

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

Ag-Pd bimetallic nanocrystals (NCs) with tunable compositions and narrow size distributions were produced by a one-pot synthesis. The NC growth process was investigated by time-dependent TEM, XRD, and UV-vis studies. In the hydrodechlorination of 4-chlorophenol, the AgPd_x (x = 2, 4, 6, 9, 19) showed pronounced composition-dependent catalytic activities, leading to the AgPd₉ catalyst with excellent activity.

Original language	English
Pages (from-to)	1560-1563
Number of pages	4
Journal	ACS Catalysis
Volume	3
Issue number	7
DOIs	https://doi.org/10.1021/cs400282a
Publication status	Published - 5 Jul 2013
Externally published	Yes

Keywords

Ag
Pd
hydrodechlorination
nanocrystals

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10.1021/cs400282a

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abstract = "Ag-Pd bimetallic nanocrystals (NCs) with tunable compositions and narrow size distributions were produced by a one-pot synthesis. The NC growth process was investigated by time-dependent TEM, XRD, and UV-vis studies. In the hydrodechlorination of 4-chlorophenol, the AgPdx (x = 2, 4, 6, 9, 19) showed pronounced composition-dependent catalytic activities, leading to the AgPd9 catalyst with excellent activity.",

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author = "Hongpan Rong and Shuangfei Cai and Zhiqiang Niu and Yadong Li",

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T1 - Composition-dependent catalytic activity of bimetallic nanocrystals

T2 - AgPd-catalyzed hydrodechlorination of 4-chlorophenol

AU - Rong, Hongpan

AU - Cai, Shuangfei

AU - Niu, Zhiqiang

AU - Li, Yadong

PY - 2013/7/5

Y1 - 2013/7/5

N2 - Ag-Pd bimetallic nanocrystals (NCs) with tunable compositions and narrow size distributions were produced by a one-pot synthesis. The NC growth process was investigated by time-dependent TEM, XRD, and UV-vis studies. In the hydrodechlorination of 4-chlorophenol, the AgPdx (x = 2, 4, 6, 9, 19) showed pronounced composition-dependent catalytic activities, leading to the AgPd9 catalyst with excellent activity.

AB - Ag-Pd bimetallic nanocrystals (NCs) with tunable compositions and narrow size distributions were produced by a one-pot synthesis. The NC growth process was investigated by time-dependent TEM, XRD, and UV-vis studies. In the hydrodechlorination of 4-chlorophenol, the AgPdx (x = 2, 4, 6, 9, 19) showed pronounced composition-dependent catalytic activities, leading to the AgPd9 catalyst with excellent activity.

KW - Ag

KW - Pd

KW - hydrodechlorination

KW - nanocrystals

UR - http://www.scopus.com/inward/record.url?scp=84879916808&partnerID=8YFLogxK

U2 - 10.1021/cs400282a

DO - 10.1021/cs400282a

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JO - ACS Catalysis

JF - ACS Catalysis

IS - 7

ER -

Composition-dependent catalytic activity of bimetallic nanocrystals: AgPd-catalyzed hydrodechlorination of 4-chlorophenol

Abstract

Keywords

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