Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides

Jiadong Zhou; Chao Zhu; Yao Zhou; Jichen Dong; Peiling Li; Zhaowei Zhang; Zhen Wang; Yung Chang Lin; Jia Shi; Runwu Zhang; Yanzhen Zheng; Huimei Yu; Bijun Tang; Fucai Liu; Lin Wang; Liwei Liu; Gui Bin Liu; Weida Hu; Yanfeng Gao; Haitao Yang; Weibo Gao; Li Lu; Yeliang Wang; Kazu Suenaga; Guangtong Liu; Feng Ding; Yugui Yao; Zheng Liu

doi:10.1038/s41563-022-01291-5

Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides

Jiadong Zhou^*
, Chao Zhu
, Yao Zhou
, Jichen Dong
, Peiling Li
, Zhaowei Zhang
, Zhen Wang
, Yung Chang Lin
, Jia Shi
, Runwu Zhang
, Yanzhen Zheng
, Huimei Yu
, Bijun Tang
, Fucai Liu
, Lin Wang
, Liwei Liu
, Gui Bin Liu
, Weida Hu
, Yanfeng Gao
, Haitao Yang

Weibo Gao, Li Lu, Yeliang Wang^*, Kazu Suenaga, Guangtong Liu, Feng Ding, Yugui Yao^*, Zheng Liu^*

^*Corresponding author for this work

Nanyang Technological University
Southeast University, Nanjing
Beijing Institute of Technology
Institute for Basic Science
CAS - Institute of Chemistry
CAS - Institute of Physics
CAS - Shanghai Institute of Technical Physics
The University of Osaka
National University of Singapore
University of Science and Technology Beijing
East China University of Science and Technology
University of Electronic Science and Technology of China
Nanjing Tech University
Shanghai University
Songshan Lake Materials Laboratory
Ulsan National Institute of Science and Technology
Research Techno Plaza Singapore

Research output: Contribution to journal › Article › peer-review

153 Citations (Scopus)

Abstract

Two-dimensional (2D) materials with multiphase, multielement crystals such as transition metal chalcogenides (TMCs) (based on V, Cr, Mn, Fe, Cd, Pt and Pd) and transition metal phosphorous chalcogenides (TMPCs) offer a unique platform to explore novel physical phenomena. However, the synthesis of a single-phase/single-composition crystal of these 2D materials via chemical vapour deposition is still challenging. Here we unravel a competitive-chemical-reaction-based growth mechanism to manipulate the nucleation and growth rate. Based on the growth mechanism, 67 types of TMCs and TMPCs with a defined phase, controllable structure and tunable component can be realized. The ferromagnetism and superconductivity in FeX_y can be tuned by the y value, such as superconductivity observed in FeX and ferromagnetism in FeS₂ monolayers, demonstrating the high quality of as-grown 2D materials. This work paves the way for the multidisciplinary exploration of 2D TMPCs and TMCs with unique properties.

Original language	English
Pages (from-to)	450-458
Number of pages	9
Journal	Nature Materials
Volume	22
Issue number	4
DOIs	https://doi.org/10.1038/s41563-022-01291-5
Publication status	Published - Apr 2023

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10.1038/s41563-022-01291-5

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Zhou, J., Zhu, C., Zhou, Y., Dong, J., Li, P., Zhang, Z., Wang, Z., Lin, Y. C., Shi, J., Zhang, R., Zheng, Y., Yu, H., Tang, B., Liu, F., Wang, L., Liu, L., Liu, G. B., Hu, W., Gao, Y., ... Liu, Z. (2023). Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides. Nature Materials, 22(4), 450-458. https://doi.org/10.1038/s41563-022-01291-5

@article{71377203be9c441bab6e69464d3bc6a7,

title = "Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides",

abstract = "Two-dimensional (2D) materials with multiphase, multielement crystals such as transition metal chalcogenides (TMCs) (based on V, Cr, Mn, Fe, Cd, Pt and Pd) and transition metal phosphorous chalcogenides (TMPCs) offer a unique platform to explore novel physical phenomena. However, the synthesis of a single-phase/single-composition crystal of these 2D materials via chemical vapour deposition is still challenging. Here we unravel a competitive-chemical-reaction-based growth mechanism to manipulate the nucleation and growth rate. Based on the growth mechanism, 67 types of TMCs and TMPCs with a defined phase, controllable structure and tunable component can be realized. The ferromagnetism and superconductivity in FeXy can be tuned by the y value, such as superconductivity observed in FeX and ferromagnetism in FeS2 monolayers, demonstrating the high quality of as-grown 2D materials. This work paves the way for the multidisciplinary exploration of 2D TMPCs and TMCs with unique properties.",

author = "Jiadong Zhou and Chao Zhu and Yao Zhou and Jichen Dong and Peiling Li and Zhaowei Zhang and Zhen Wang and Lin, \{Yung Chang\} and Jia Shi and Runwu Zhang and Yanzhen Zheng and Huimei Yu and Bijun Tang and Fucai Liu and Lin Wang and Liwei Liu and Liu, \{Gui Bin\} and Weida Hu and Yanfeng Gao and Haitao Yang and Weibo Gao and Li Lu and Yeliang Wang and Kazu Suenaga and Guangtong Liu and Feng Ding and Yugui Yao and Zheng Liu",

note = "Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive licence to Springer Nature Limited.",

year = "2023",

month = apr,

doi = "10.1038/s41563-022-01291-5",

language = "English",

volume = "22",

pages = "450--458",

journal = "Nature Materials",

issn = "1476-1122",

publisher = "Nature Publishing Group",

number = "4",

}

Zhou, J, Zhu, C, Zhou, Y, Dong, J, Li, P, Zhang, Z, Wang, Z, Lin, YC, Shi, J, Zhang, R, Zheng, Y, Yu, H, Tang, B, Liu, F, Wang, L, Liu, L , Liu, GB, Hu, W, Gao, Y, Yang, H, Gao, W, Lu, L, Wang, Y, Suenaga, K, Liu, G, Ding, F, Yao, Y & Liu, Z 2023, 'Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides', Nature Materials, vol. 22, no. 4, pp. 450-458. https://doi.org/10.1038/s41563-022-01291-5

TY - JOUR

T1 - Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides

AU - Zhou, Jiadong

AU - Zhu, Chao

AU - Zhou, Yao

AU - Dong, Jichen

AU - Li, Peiling

AU - Zhang, Zhaowei

AU - Wang, Zhen

AU - Lin, Yung Chang

AU - Shi, Jia

AU - Zhang, Runwu

AU - Zheng, Yanzhen

AU - Yu, Huimei

AU - Tang, Bijun

AU - Liu, Fucai

AU - Wang, Lin

AU - Liu, Liwei

AU - Liu, Gui Bin

AU - Hu, Weida

AU - Gao, Yanfeng

AU - Yang, Haitao

AU - Gao, Weibo

AU - Lu, Li

AU - Wang, Yeliang

AU - Suenaga, Kazu

AU - Liu, Guangtong

AU - Ding, Feng

AU - Yao, Yugui

AU - Liu, Zheng

PY - 2023/4

Y1 - 2023/4

N2 - Two-dimensional (2D) materials with multiphase, multielement crystals such as transition metal chalcogenides (TMCs) (based on V, Cr, Mn, Fe, Cd, Pt and Pd) and transition metal phosphorous chalcogenides (TMPCs) offer a unique platform to explore novel physical phenomena. However, the synthesis of a single-phase/single-composition crystal of these 2D materials via chemical vapour deposition is still challenging. Here we unravel a competitive-chemical-reaction-based growth mechanism to manipulate the nucleation and growth rate. Based on the growth mechanism, 67 types of TMCs and TMPCs with a defined phase, controllable structure and tunable component can be realized. The ferromagnetism and superconductivity in FeXy can be tuned by the y value, such as superconductivity observed in FeX and ferromagnetism in FeS2 monolayers, demonstrating the high quality of as-grown 2D materials. This work paves the way for the multidisciplinary exploration of 2D TMPCs and TMCs with unique properties.

AB - Two-dimensional (2D) materials with multiphase, multielement crystals such as transition metal chalcogenides (TMCs) (based on V, Cr, Mn, Fe, Cd, Pt and Pd) and transition metal phosphorous chalcogenides (TMPCs) offer a unique platform to explore novel physical phenomena. However, the synthesis of a single-phase/single-composition crystal of these 2D materials via chemical vapour deposition is still challenging. Here we unravel a competitive-chemical-reaction-based growth mechanism to manipulate the nucleation and growth rate. Based on the growth mechanism, 67 types of TMCs and TMPCs with a defined phase, controllable structure and tunable component can be realized. The ferromagnetism and superconductivity in FeXy can be tuned by the y value, such as superconductivity observed in FeX and ferromagnetism in FeS2 monolayers, demonstrating the high quality of as-grown 2D materials. This work paves the way for the multidisciplinary exploration of 2D TMPCs and TMCs with unique properties.

UR - https://www.scopus.com/pages/publications/85132563171

U2 - 10.1038/s41563-022-01291-5

DO - 10.1038/s41563-022-01291-5

M3 - Article

C2 - 35739274

AN - SCOPUS:85132563171

SN - 1476-1122

VL - 22

SP - 450

EP - 458

JO - Nature Materials

JF - Nature Materials

IS - 4

ER -

Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides

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