Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

Xin Xiong Li; Xiang Ma; Wen Xu Zheng; Yan Jie Qi; Shou Tian Zheng; Guo Yu Yang

doi:10.1021/acs.inorgchem.6b01453

Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

Xin Xiong Li
, Xiang Ma
, Wen Xu Zheng
, Yan Jie Qi
, Shou Tian Zheng^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Fuzhou University

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu₈I₆]²⁺ and eight Anderson-type anionic POMs [HCrMo₆O₁₈(OH)₆]^2- cross-linked by a tripodal alcohol derivative.

Original language	English
Pages (from-to)	8257-8259
Number of pages	3
Journal	Inorganic Chemistry
Volume	55
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01453
Publication status	Published - 6 Sept 2016

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title = "Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties",

abstract = "A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6]2+ and eight Anderson-type anionic POMs [HCrMo6O18(OH)6]2- cross-linked by a tripodal alcohol derivative.",

author = "Li, \{Xin Xiong\} and Xiang Ma and Zheng, \{Wen Xu\} and Qi, \{Yan Jie\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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doi = "10.1021/acs.inorgchem.6b01453",

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journal = "Inorganic Chemistry",

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T1 - Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster

T2 - Synthetic Strategy, Structure, and Properties

AU - Li, Xin Xiong

AU - Ma, Xiang

AU - Zheng, Wen Xu

AU - Qi, Yan Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2016/9/6

Y1 - 2016/9/6

N2 - A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6]2+ and eight Anderson-type anionic POMs [HCrMo6O18(OH)6]2- cross-linked by a tripodal alcohol derivative.

AB - A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6]2+ and eight Anderson-type anionic POMs [HCrMo6O18(OH)6]2- cross-linked by a tripodal alcohol derivative.

UR - https://www.scopus.com/pages/publications/84986218248

U2 - 10.1021/acs.inorgchem.6b01453

DO - 10.1021/acs.inorgchem.6b01453

M3 - Article

AN - SCOPUS:84986218248

SN - 0020-1669

VL - 55

SP - 8257

EP - 8259

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

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