Comparison of liquid phase ion speciation in DEAB-CO2- H2O system with IPAB-CO2-H2O system using 13C NMR techniques

Bin Liu; Helei Liu; Zhiwu Liang; Kaiyun Fu; Raphael Idem; Wichitpan Rongwong; Paitoon Tontiwachwuthikul

doi:10.1016/j.egypro.2014.11.201

Comparison of liquid phase ion speciation in DEAB-CO2- H₂O system with IPAB-CO2-H₂O system using ¹³C NMR techniques

Bin Liu
, Helei Liu
, Zhiwu Liang^*
, Kaiyun Fu
, Raphael Idem
, Wichitpan Rongwong
, Paitoon Tontiwachwuthikul

^*Corresponding author for this work

Hunan University
University of Regina

Research output: Contribution to journal › Conference article › peer-review

Abstract

The ¹³C NMR techniques were selected to investigate the ion speciation in both DEAB and IPAB solvents. Calibration equations were established to quantify the exact ion concentration of free amines and protonated amines at different absorption times. The results show that the NMR method can be used to obtain both qualitative and quantitative information of the amine-CO2-H₂O system. It is also the first time to monitor the components in the new solvent (IPAB) and establish its VLE model.

Original language	English
Pages (from-to)	1919-1926
Number of pages	8
Journal	Energy Procedia
Volume	63
DOIs	https://doi.org/10.1016/j.egypro.2014.11.201
Publication status	Published - 2014
Externally published	Yes
Event	12th International Conference on Greenhouse Gas Control Technologies, GHGT 2014 - Austin, United States Duration: 5 Oct 2014 → 9 Oct 2014

Keywords

Absorption
C NMR
Carbon dioxide
Quantification
Relaxation time

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10.1016/j.egypro.2014.11.201

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title = "Comparison of liquid phase ion speciation in DEAB-CO2- H2O system with IPAB-CO2-H2O system using 13C NMR techniques",

abstract = "The 13C NMR techniques were selected to investigate the ion speciation in both DEAB and IPAB solvents. Calibration equations were established to quantify the exact ion concentration of free amines and protonated amines at different absorption times. The results show that the NMR method can be used to obtain both qualitative and quantitative information of the amine-CO2-H2O system. It is also the first time to monitor the components in the new solvent (IPAB) and establish its VLE model.",

keywords = "Absorption, C NMR, Carbon dioxide, Quantification, Relaxation time",

author = "Bin Liu and Helei Liu and Zhiwu Liang and Kaiyun Fu and Raphael Idem and Wichitpan Rongwong and Paitoon Tontiwachwuthikul",

note = "Publisher Copyright: {\textcopyright} 2014 The Authors Published by Elsevier Ltd.; 12th International Conference on Greenhouse Gas Control Technologies, GHGT 2014 ; Conference date: 05-10-2014 Through 09-10-2014",

year = "2014",

doi = "10.1016/j.egypro.2014.11.201",

language = "English",

volume = "63",

pages = "1919--1926",

journal = "Energy Procedia",

issn = "1876-6102",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Comparison of liquid phase ion speciation in DEAB-CO2- H2O system with IPAB-CO2-H2O system using 13C NMR techniques

AU - Liu, Bin

AU - Liu, Helei

AU - Liang, Zhiwu

AU - Fu, Kaiyun

AU - Idem, Raphael

AU - Rongwong, Wichitpan

AU - Tontiwachwuthikul, Paitoon

PY - 2014

Y1 - 2014

N2 - The 13C NMR techniques were selected to investigate the ion speciation in both DEAB and IPAB solvents. Calibration equations were established to quantify the exact ion concentration of free amines and protonated amines at different absorption times. The results show that the NMR method can be used to obtain both qualitative and quantitative information of the amine-CO2-H2O system. It is also the first time to monitor the components in the new solvent (IPAB) and establish its VLE model.

AB - The 13C NMR techniques were selected to investigate the ion speciation in both DEAB and IPAB solvents. Calibration equations were established to quantify the exact ion concentration of free amines and protonated amines at different absorption times. The results show that the NMR method can be used to obtain both qualitative and quantitative information of the amine-CO2-H2O system. It is also the first time to monitor the components in the new solvent (IPAB) and establish its VLE model.

KW - Absorption

KW - C NMR

KW - Carbon dioxide

KW - Quantification

KW - Relaxation time

UR - https://www.scopus.com/pages/publications/84922858368

U2 - 10.1016/j.egypro.2014.11.201

DO - 10.1016/j.egypro.2014.11.201

M3 - Conference article

AN - SCOPUS:84922858368

SN - 1876-6102

VL - 63

SP - 1919

EP - 1926

JO - Energy Procedia

JF - Energy Procedia

T2 - 12th International Conference on Greenhouse Gas Control Technologies, GHGT 2014

Y2 - 5 October 2014 through 9 October 2014

ER -

Comparison of liquid phase ion speciation in DEAB-CO2- H₂O system with IPAB-CO2-H₂O system using ¹³C NMR techniques

Abstract

Keywords

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