Comparative Study of Various Pyrazole-based Anions: A Promising Family of Ionic Derivatives as Insensitive Energetic Materials

Ping Yin; Lauren A. Mitchell; Damon A. Parrish; Jean'ne M. Shreeve

doi:10.1002/asia.201601615

Comparative Study of Various Pyrazole-based Anions: A Promising Family of Ionic Derivatives as Insensitive Energetic Materials

Ping Yin
, Lauren A. Mitchell
, Damon A. Parrish
, Jean'ne M. Shreeve^*

^*Corresponding author for this work

University of Idaho
University of Minnesota Twin Cities
Naval Research Laboratory

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

In the design of advanced energetic materials, high-density explosophores play a pivotal role because of their remarkable enhancement of both density and molecular stability. Using diversified functionalization strategies, a comparative study involving various nitropyrazole anions shows that these are crucially important in determining performance and stability. A promising family of pyrazole-based energetic ionic derivatives were synthesized and characterized by NMR and IR spectroscopies, and elemental analysis. Among them, 7, 8, 11–13 exhibit favorable overall performance as energetic materials.

Original language	English
Pages (from-to)	378-384
Number of pages	7
Journal	Chemistry - An Asian Journal
Volume	12
Issue number	3
DOIs	https://doi.org/10.1002/asia.201601615
Publication status	Published - 1 Feb 2017
Externally published	Yes

Keywords

detonation properties
energetic materials
ionic derivatives
nitrogen-rich compounds
pyrazole-based anions

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10.1002/asia.201601615

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title = "Comparative Study of Various Pyrazole-based Anions: A Promising Family of Ionic Derivatives as Insensitive Energetic Materials",

abstract = "In the design of advanced energetic materials, high-density explosophores play a pivotal role because of their remarkable enhancement of both density and molecular stability. Using diversified functionalization strategies, a comparative study involving various nitropyrazole anions shows that these are crucially important in determining performance and stability. A promising family of pyrazole-based energetic ionic derivatives were synthesized and characterized by NMR and IR spectroscopies, and elemental analysis. Among them, 7, 8, 11{\textendash}13 exhibit favorable overall performance as energetic materials.",

keywords = "detonation properties, energetic materials, ionic derivatives, nitrogen-rich compounds, pyrazole-based anions",

author = "Ping Yin and Mitchell, \{Lauren A.\} and Parrish, \{Damon A.\} and Shreeve, \{Jean'ne M.\}",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

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doi = "10.1002/asia.201601615",

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T2 - A Promising Family of Ionic Derivatives as Insensitive Energetic Materials

AU - Yin, Ping

AU - Mitchell, Lauren A.

AU - Parrish, Damon A.

AU - Shreeve, Jean'ne M.

PY - 2017/2/1

Y1 - 2017/2/1

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AB - In the design of advanced energetic materials, high-density explosophores play a pivotal role because of their remarkable enhancement of both density and molecular stability. Using diversified functionalization strategies, a comparative study involving various nitropyrazole anions shows that these are crucially important in determining performance and stability. A promising family of pyrazole-based energetic ionic derivatives were synthesized and characterized by NMR and IR spectroscopies, and elemental analysis. Among them, 7, 8, 11–13 exhibit favorable overall performance as energetic materials.

KW - detonation properties

KW - energetic materials

KW - ionic derivatives

KW - nitrogen-rich compounds

KW - pyrazole-based anions

UR - https://www.scopus.com/pages/publications/85009486556

U2 - 10.1002/asia.201601615

DO - 10.1002/asia.201601615

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VL - 12

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JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 3

ER -

Comparative Study of Various Pyrazole-based Anions: A Promising Family of Ionic Derivatives as Insensitive Energetic Materials

Abstract

Keywords

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