Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

Jupeng Chen; Xiaolin Wu; Shaowen Zhang; Xiangqian Yan; Xiaolu Wu; Qingbin Cao; Huan Xu; Xiaofang Li

doi:10.1039/d2py00490a

Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

Jupeng Chen, Xiaolin Wu, Shaowen Zhang^*, Xiangqian Yan, Xiaolu Wu, Qingbin Cao, Huan Xu, Xiaofang Li^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Commercially available palladium salts (1-4) (1: PdCl₂; 2: PdCl₂(CH₃CN)₂; 3: PdCl₂(C₆H₅CN)₂; and 4: Pd(OAc)₂) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl-C ≡ C-C₆H₄R (a-j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.

Original language	English
Pages (from-to)	3870-3875
Number of pages	6
Journal	Polymer Chemistry
Volume	13
Issue number	26
DOIs	https://doi.org/10.1039/d2py00490a
Publication status	Published - 27 Jun 2022

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title = "Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air",

abstract = "Commercially available palladium salts (1-4) (1: PdCl2; 2: PdCl2(CH3CN)2; 3: PdCl2(C6H5CN)2; and 4: Pd(OAc)2) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl-C ≡ C-C6H4R (a-j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.",

author = "Jupeng Chen and Xiaolin Wu and Shaowen Zhang and Xiangqian Yan and Xiaolu Wu and Qingbin Cao and Huan Xu and Xiaofang Li",

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T1 - Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

AU - Chen, Jupeng

AU - Wu, Xiaolin

AU - Zhang, Shaowen

AU - Yan, Xiangqian

AU - Wu, Xiaolu

AU - Cao, Qingbin

AU - Xu, Huan

AU - Li, Xiaofang

PY - 2022/6/27

Y1 - 2022/6/27

N2 - Commercially available palladium salts (1-4) (1: PdCl2; 2: PdCl2(CH3CN)2; 3: PdCl2(C6H5CN)2; and 4: Pd(OAc)2) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl-C ≡ C-C6H4R (a-j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.

AB - Commercially available palladium salts (1-4) (1: PdCl2; 2: PdCl2(CH3CN)2; 3: PdCl2(C6H5CN)2; and 4: Pd(OAc)2) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl-C ≡ C-C6H4R (a-j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.

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U2 - 10.1039/d2py00490a

DO - 10.1039/d2py00490a

M3 - Article

AN - SCOPUS:85133211035

SN - 1759-9954

VL - 13

SP - 3870

EP - 3875

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 26

ER -

Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

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