Cocrystallization of chelating-energetic-material and metal-organic-framework with the nitrogen-rich ligand bis(tetrazole)methane

Rui Zhang; Wen Chao Tong; Yan Lan Wang; Jian Chao Liu; Li Yang

doi:10.1080/15421406.2018.1553757

Cocrystallization of chelating-energetic-material and metal-organic-framework with the nitrogen-rich ligand bis(tetrazole)methane

Rui Zhang
, Wen Chao Tong^*
, Yan Lan Wang
, Jian Chao Liu
, Li Yang

^*Corresponding author for this work

School of Mechatronical Engineering

National Key Laboratory of Applied Physics and Chemistry
Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two recently introduced concepts in the design of high-energy-density materials (HEDMs), namely Metal–organic frameworks (MOFs) and Chelating energetic material (CEM), have been applied in the synthesis of the energetic manganese (II) compound {[Mn(btm)(H₂O)₃]₂·H₂O}_n (1) (H₂btm = bis(tetrazole)methane), cocrystalized by a dinuclear CEM and a 1D MOF, which is characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that 1 crystallizes in the monoclinic space group P_21/c. The Mn²⁺ was hexa-coordinated with two btm groups and three water molecules. Btm presents tridentate coordination modes. The thermal decomposition mechanism of 1 was studied by differential scanning calorimetry (DSC). The non-isothermal kinetics parameters were calculated by the Kissinger’s method and Ozawa-Doyle’s method, respectively. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.

Original language	English
Pages (from-to)	132-139
Number of pages	8
Journal	Molecular Crystals and Liquid Crystals
Volume	668
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2018.1553757
Publication status	Published - 13 Jun 2018

Keywords

Chelate
Cocrystallization
Crystal
MOF

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10.1080/15421406.2018.1553757

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@article{d3d20f8e04874401a74e1124d4a78b41,

title = "Cocrystallization of chelating-energetic-material and metal-organic-framework with the nitrogen-rich ligand bis(tetrazole)methane",

abstract = "Two recently introduced concepts in the design of high-energy-density materials (HEDMs), namely Metal–organic frameworks (MOFs) and Chelating energetic material (CEM), have been applied in the synthesis of the energetic manganese (II) compound \{[Mn(btm)(H2O)3]2·H2O\}n (1) (H2btm = bis(tetrazole)methane), cocrystalized by a dinuclear CEM and a 1D MOF, which is characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that 1 crystallizes in the monoclinic space group P21/c. The Mn2+ was hexa-coordinated with two btm groups and three water molecules. Btm presents tridentate coordination modes. The thermal decomposition mechanism of 1 was studied by differential scanning calorimetry (DSC). The non-isothermal kinetics parameters were calculated by the Kissinger{\textquoteright}s method and Ozawa-Doyle{\textquoteright}s method, respectively. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.",

keywords = "Chelate, Cocrystallization, Crystal, MOF",

author = "Rui Zhang and Tong, \{Wen Chao\} and Wang, \{Yan Lan\} and Liu, \{Jian Chao\} and Li Yang",

note = "Publisher Copyright: {\textcopyright} 2018, {\textcopyright} 2018 Taylor \& Francis Group, LLC.",

year = "2018",

month = jun,

day = "13",

doi = "10.1080/15421406.2018.1553757",

language = "English",

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pages = "132--139",

journal = "Molecular Crystals and Liquid Crystals",

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TY - JOUR

T1 - Cocrystallization of chelating-energetic-material and metal-organic-framework with the nitrogen-rich ligand bis(tetrazole)methane

AU - Zhang, Rui

AU - Tong, Wen Chao

AU - Wang, Yan Lan

AU - Liu, Jian Chao

AU - Yang, Li

PY - 2018/6/13

Y1 - 2018/6/13

N2 - Two recently introduced concepts in the design of high-energy-density materials (HEDMs), namely Metal–organic frameworks (MOFs) and Chelating energetic material (CEM), have been applied in the synthesis of the energetic manganese (II) compound {[Mn(btm)(H2O)3]2·H2O}n (1) (H2btm = bis(tetrazole)methane), cocrystalized by a dinuclear CEM and a 1D MOF, which is characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that 1 crystallizes in the monoclinic space group P21/c. The Mn2+ was hexa-coordinated with two btm groups and three water molecules. Btm presents tridentate coordination modes. The thermal decomposition mechanism of 1 was studied by differential scanning calorimetry (DSC). The non-isothermal kinetics parameters were calculated by the Kissinger’s method and Ozawa-Doyle’s method, respectively. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.

AB - Two recently introduced concepts in the design of high-energy-density materials (HEDMs), namely Metal–organic frameworks (MOFs) and Chelating energetic material (CEM), have been applied in the synthesis of the energetic manganese (II) compound {[Mn(btm)(H2O)3]2·H2O}n (1) (H2btm = bis(tetrazole)methane), cocrystalized by a dinuclear CEM and a 1D MOF, which is characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that 1 crystallizes in the monoclinic space group P21/c. The Mn2+ was hexa-coordinated with two btm groups and three water molecules. Btm presents tridentate coordination modes. The thermal decomposition mechanism of 1 was studied by differential scanning calorimetry (DSC). The non-isothermal kinetics parameters were calculated by the Kissinger’s method and Ozawa-Doyle’s method, respectively. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.

KW - Chelate

KW - Cocrystallization

KW - Crystal

KW - MOF

UR - https://www.scopus.com/pages/publications/85063873517

U2 - 10.1080/15421406.2018.1553757

DO - 10.1080/15421406.2018.1553757

M3 - Article

AN - SCOPUS:85063873517

SN - 1542-1406

VL - 668

SP - 132

EP - 139

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Cocrystallization of chelating-energetic-material and metal-organic-framework with the nitrogen-rich ligand bis(tetrazole)methane

Abstract

Keywords

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