Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

Bao Hua Xu; Xu Qing Peng; Zhi Wei Xu; Yi Zhi Li; Hong Yan

doi:10.1021/ic801199e

Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

Bao Hua Xu
, Xu Qing Peng
, Zhi Wei Xu
, Yi Zhi Li
, Hong Yan^*

^*Corresponding author for this work

Nanjing University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp₂Co] ⁺[Co(S₂C₂B₁₀H₁₀) ₂]^-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (¹H, ¹¹B, ¹³C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

Original language	English
Pages (from-to)	7928-7933
Number of pages	6
Journal	Inorganic Chemistry
Volume	47
Issue number	17
DOIs	https://doi.org/10.1021/ic801199e
Publication status	Published - 1 Sept 2008
Externally published	Yes

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title = "Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes",

abstract = "Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.",

author = "Xu, \{Bao Hua\} and Peng, \{Xu Qing\} and Xu, \{Zhi Wei\} and Li, \{Yi Zhi\} and Hong Yan",

year = "2008",

month = sep,

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doi = "10.1021/ic801199e",

language = "English",

volume = "47",

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journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

AU - Xu, Bao Hua

AU - Peng, Xu Qing

AU - Xu, Zhi Wei

AU - Li, Yi Zhi

AU - Yan, Hong

PY - 2008/9/1

Y1 - 2008/9/1

N2 - Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

AB - Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

UR - https://www.scopus.com/pages/publications/51849151584

U2 - 10.1021/ic801199e

DO - 10.1021/ic801199e

M3 - Article

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SN - 0020-1669

VL - 47

SP - 7928

EP - 7933

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

Abstract

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