Cobalt(III)-mediated disulfuration and hydrosulfuration of alkynes

Bao Hua Xu, Xu Qing Peng, Zhi Wei Xu, Yi Zhi Li, Hong Yan*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

Disulfuration and hydrosulfuration of alkynes mediated by an unusual square-planar tetrathiolate cobalt(III) complex [Cp2Co] +[Co(S2C2B10H10) 2]-, 1, lead to a series of cobalt-free carboranyl vinyl sulfides 2-9. All new complexes 1, 2, 3, 4, 5, 6, 7, 8, and 9 were characterized by NMR spectroscopy (1H, 11B, 13C), and X-ray structural analyses were performed for 1, 2, 3, 5, 6, 7, and 9.

Original languageEnglish
Pages (from-to)7928-7933
Number of pages6
JournalInorganic Chemistry
Volume47
Issue number17
DOIs
Publication statusPublished - 1 Sept 2008
Externally publishedYes

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