Cluster Organic Framework Based on Er3 and Cu5 Cluster Units

Wei Hui Fang; Guo Yu Yang

doi:10.1007/s10876-014-0724-2

Cluster Organic Framework Based on Er₃ and Cu₅ Cluster Units

Wei Hui Fang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

Abstract

A novel cluster organic framework, Er₃Cu₅I₄L₁₀(H₂O) (1, L = 4-pyridin-3-yl-benzonate), has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows [Er₃(COO)₆]³⁺ (Er₃) clusters are linked by carboxylate groups generating one dimensional wave-like chain, which further extended by Cu₅I₄ ⁺ (Cu₅) clusters into three dimensional heterometallic cluster organic framework. From the perspective of topology, such framework defines a new (7,9)-connected net, considering Er₃ and Cu₅ cores as the nodes. Furthermore, the elemental analysis, powder X-ray diffraction, infrared spectra and thermogravimetric analysis are also studied.

Original language	English
Pages (from-to)	1479-1488
Number of pages	10
Journal	Journal of Cluster Science
Volume	25
Issue number	5
DOIs	https://doi.org/10.1007/s10876-014-0724-2
Publication status	Published - 1 Sept 2014
Externally published	Yes

Keywords

Cluster organic framework
Copper halide cluster
Heterometallic
Hydrothermal synthesis
Lanthanide cluster

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10.1007/s10876-014-0724-2

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@article{d57fe49b7f944fa78fd0a7d3a8c56729,

title = "Cluster Organic Framework Based on Er3 and Cu5 Cluster Units",

abstract = "A novel cluster organic framework, Er3Cu5I4L10(H2O) (1, L = 4-pyridin-3-yl-benzonate), has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows [Er3(COO)6]3+ (Er3) clusters are linked by carboxylate groups generating one dimensional wave-like chain, which further extended by Cu5I4 + (Cu5) clusters into three dimensional heterometallic cluster organic framework. From the perspective of topology, such framework defines a new (7,9)-connected net, considering Er3 and Cu5 cores as the nodes. Furthermore, the elemental analysis, powder X-ray diffraction, infrared spectra and thermogravimetric analysis are also studied.",

keywords = "Cluster organic framework, Copper halide cluster, Heterometallic, Hydrothermal synthesis, Lanthanide cluster",

author = "Fang, \{Wei Hui\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2014, Springer Science+Business Media New York.",

year = "2014",

month = sep,

day = "1",

doi = "10.1007/s10876-014-0724-2",

language = "English",

volume = "25",

pages = "1479--1488",

journal = "Journal of Cluster Science",

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number = "5",

}

TY - JOUR

T1 - Cluster Organic Framework Based on Er3 and Cu5 Cluster Units

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2014/9/1

Y1 - 2014/9/1

N2 - A novel cluster organic framework, Er3Cu5I4L10(H2O) (1, L = 4-pyridin-3-yl-benzonate), has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows [Er3(COO)6]3+ (Er3) clusters are linked by carboxylate groups generating one dimensional wave-like chain, which further extended by Cu5I4 + (Cu5) clusters into three dimensional heterometallic cluster organic framework. From the perspective of topology, such framework defines a new (7,9)-connected net, considering Er3 and Cu5 cores as the nodes. Furthermore, the elemental analysis, powder X-ray diffraction, infrared spectra and thermogravimetric analysis are also studied.

AB - A novel cluster organic framework, Er3Cu5I4L10(H2O) (1, L = 4-pyridin-3-yl-benzonate), has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows [Er3(COO)6]3+ (Er3) clusters are linked by carboxylate groups generating one dimensional wave-like chain, which further extended by Cu5I4 + (Cu5) clusters into three dimensional heterometallic cluster organic framework. From the perspective of topology, such framework defines a new (7,9)-connected net, considering Er3 and Cu5 cores as the nodes. Furthermore, the elemental analysis, powder X-ray diffraction, infrared spectra and thermogravimetric analysis are also studied.

KW - Cluster organic framework

KW - Copper halide cluster

KW - Heterometallic

KW - Hydrothermal synthesis

KW - Lanthanide cluster

UR - https://www.scopus.com/pages/publications/84957438295

U2 - 10.1007/s10876-014-0724-2

DO - 10.1007/s10876-014-0724-2

M3 - Article

AN - SCOPUS:84957438295

SN - 1040-7278

VL - 25

SP - 1479

EP - 1488

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 5

ER -

Cluster Organic Framework Based on Er₃ and Cu₅ Cluster Units

Abstract

Keywords

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