TY - JOUR
T1 - Circularly Polarized Luminescent π-Conjugated Chiral Nanorings and Nanobelts
AU - Xue, Yuting
AU - Shi, Yafei
AU - Chen, Pangkuan
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2024/6/26
Y1 - 2024/6/26
N2 - Molecular chirality plays a pivotal role across the disciplines of chemical and physical sciences, as well as holding significant implications in the realms of medicine and technology. Chiral macrocycles have attracted recent interests in synthetic chemistry, material science, and supramolecular chemistry. Due to the cyclic arrangements of stereogenic elements or special orientations confined in the rigid structures, π-conjugated chiral macrocycles are expected to be highly luminescent, and configurationally stable, and thus serve to develop high-performance chiroptical materials. Given the rapid progress achieved in this new area in recent years, it is significant to highlight new concepts and breakthroughs. This minireview will offer the overview of a wide range of π-conjugated chiral macrocycles from traditional molecules which include the axially, helically, and planar chiral skeletons to the new chiral nanobelts with a focus on the structure-function relationship between chiral molecules and the unique chiroptical properties.
AB - Molecular chirality plays a pivotal role across the disciplines of chemical and physical sciences, as well as holding significant implications in the realms of medicine and technology. Chiral macrocycles have attracted recent interests in synthetic chemistry, material science, and supramolecular chemistry. Due to the cyclic arrangements of stereogenic elements or special orientations confined in the rigid structures, π-conjugated chiral macrocycles are expected to be highly luminescent, and configurationally stable, and thus serve to develop high-performance chiroptical materials. Given the rapid progress achieved in this new area in recent years, it is significant to highlight new concepts and breakthroughs. This minireview will offer the overview of a wide range of π-conjugated chiral macrocycles from traditional molecules which include the axially, helically, and planar chiral skeletons to the new chiral nanobelts with a focus on the structure-function relationship between chiral molecules and the unique chiroptical properties.
KW - chiral macrocycles
KW - circularly polarized luminescence
KW - nanobelts
KW - π-conjugation
UR - http://www.scopus.com/inward/record.url?scp=85193533267&partnerID=8YFLogxK
U2 - 10.1002/adom.202303322
DO - 10.1002/adom.202303322
M3 - Review article
AN - SCOPUS:85193533267
SN - 2195-1071
VL - 12
JO - Advanced Optical Materials
JF - Advanced Optical Materials
IS - 18
M1 - 2303322
ER -